Dehalogenative aromatization of perchlorofluoroalicyclic compounds C6Cl6F6, C10Cl8F8 and C5Cl4F5N in the vapour phase or in solution Full article
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Output data | Year: 2004, Volume: 125, Number: 10, Pages: 1431-1435 Pages count : DOI: 10.1016/j.jfluchem.2004.04.015 | ||
| Tags | dehalogenation; hexafluorobenzene; octafluoronaphthalene; pentafluoropyridine | ||
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Abstract:
Dehalogenation of perhalogenated cyclohexanes C6Cl6F6, 1-azacyclohexenes C5Cl4F5N and bicyclo[4.4.0]dec-1(6)-enes C10Cl8F8 in the vapour phase over iron filings at 350-500 degreesC and in solution with Zn and additivities (Cu, NiCl2.6H(2)O + bpy) at 80 degreesC (heterogeneous reaction) or with P(NEt2)(3) at 20 degreesC (homogeneous reaction) was studied. In all cases, perfluoroarenes, chloroperfluoroarenes and dichloroperfluoroarenes (benzenes, naphthalenes and pyridines) were obtained in good overall yield. (C) 2004 Elsevier B.V. All rights reserved.
Cite:
Bardin V.
, Trukhin D.
, Adonin N.
, Starichenko V.
Dehalogenative aromatization of perchlorofluoroalicyclic compounds C6Cl6F6, C10Cl8F8 and C5Cl4F5N in the vapour phase or in solution
Journal of Fluorine Chemistry. 2004. V.125. N10. P.1431-1435. DOI: 10.1016/j.jfluchem.2004.04.015 WOS Scopus РИНЦ OpenAlex
Dehalogenative aromatization of perchlorofluoroalicyclic compounds C6Cl6F6, C10Cl8F8 and C5Cl4F5N in the vapour phase or in solution
Journal of Fluorine Chemistry. 2004. V.125. N10. P.1431-1435. DOI: 10.1016/j.jfluchem.2004.04.015 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Oct 1, 2004 |
Identifiers:
| Web of science: | WOS:000224445400005 |
| Scopus: | 2-s2.0-4644281650 |
| Elibrary: | 13473421 |
| OpenAlex: | W1965891959 |