Novel cyanide-bridged three-dimensional coordination polymer derived from an octahedral rhenium cluster [Re6Te8(CN)(6)](4-): Synthesis and crystal structure of [{Mn(H2O)(2)(DMF)}(2)Re6Te8(CN)(6)]center dot 2H(2)O Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2004, Volume: 45, Number: 5, Pages: 874-878 Pages count : 5 DOI: 10.1007/s10947-005-0072-z | ||||
| Tags | octahedral cluster; rhenium; chalcocyanide complex; cyanide bridge; manganese; synthesis; crystal structure | ||||
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Abstract:
The reaction of a water solution of K4Re6Te8(CN)(6) with a solution of Mn(NO3)(2) in 0.02M hydrochloric acid in the presence of DMF gave crystals of a cluster rhenium complex [{Mn(H2O)2(DMF)}(2)Re6Te8(CN)(6)].2H(2)O.. The structure of the compound was determined by single crystal X-ray diffraction (a = 12.6679(9) angstrom, b=17.4524(12)angstrom, c 9.7882(6)angstrom, beta= 105.570(6)degrees, V=2084.6(3)angstrom(3), Z=2, space group P2(1)/n, R = 0.0389). In the complex, the [Re6Te8(CN)(6)](4-) cluster anions are linked to Mn2+, cations by the cyanide bridges, the manganese cations being additionally coordinated by the DMF molecule and two water molecules. The neighboring clusters are joined by Re-C-N-Mn bridges into a three-dimensional framework possessing cavities filled with doubly disordered water molecules.
Cite:
Mironov Y.
, Solodovnikov S.
, Fedorov V.
, Gatilov Y.
Novel cyanide-bridged three-dimensional coordination polymer derived from an octahedral rhenium cluster [Re6Te8(CN)(6)](4-): Synthesis and crystal structure of [{Mn(H2O)(2)(DMF)}(2)Re6Te8(CN)(6)]center dot 2H(2)O
Journal of Structural Chemistry. 2004. V.45. N5. P.874-878. DOI: 10.1007/s10947-005-0072-z WOS Scopus РИНЦ OpenAlex
Novel cyanide-bridged three-dimensional coordination polymer derived from an octahedral rhenium cluster [Re6Te8(CN)(6)](4-): Synthesis and crystal structure of [{Mn(H2O)(2)(DMF)}(2)Re6Te8(CN)(6)]center dot 2H(2)O
Journal of Structural Chemistry. 2004. V.45. N5. P.874-878. DOI: 10.1007/s10947-005-0072-z WOS Scopus РИНЦ OpenAlex
Original:
Миронов Ю.В.
, Солодовников С.Ф.
, Федоров В.Е.
, Гатилов Ю.В.
НОВЫЙ ЦИАНОМОСТИКОВЫЙ ТРЕХМЕРНЫЙ КООРДИНАЦИОННЫЙ ПОЛИМЕР НА ОСНОВЕ ОКТАЭДРИЧЕСКОГО КЛАСТЕРА РЕНИЯ [RE6TE8(CN)6]4-: СИНТЕЗ И КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА [{MN(H2O)2(DMF)}2RE6TE8(CN)6]·2H2O
Журнал структурной химии (J STRUCT CHEM+). 2004. Т.45. №5. С.918-922. РИНЦ
НОВЫЙ ЦИАНОМОСТИКОВЫЙ ТРЕХМЕРНЫЙ КООРДИНАЦИОННЫЙ ПОЛИМЕР НА ОСНОВЕ ОКТАЭДРИЧЕСКОГО КЛАСТЕРА РЕНИЯ [RE6TE8(CN)6]4-: СИНТЕЗ И КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА [{MN(H2O)2(DMF)}2RE6TE8(CN)6]·2H2O
Журнал структурной химии (J STRUCT CHEM+). 2004. Т.45. №5. С.918-922. РИНЦ
Dates:
| Published print: | Sep 1, 2004 |
Identifiers:
| Web of science: | WOS:000230067500021 |
| Scopus: | 2-s2.0-21644448437 |
| Elibrary: | 13460941 |
| OpenAlex: | W2316089404 |