Degenerate rearrangement of long-lived 9,10-dimethyl-9-(cis-1-methyl-1-propenyl)phenanthrenium ion: 1,2-shift of the dimethylvinyl group Научная публикация
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Вых. Данные | Год: 2004, Том: 40, Номер: 7, Страницы: 966-972 Страниц : 7 DOI: 10.1023/B:RUJO.0000045186.11978.a5 | ||
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Реферат:
Dynamic NMR study showed that 9,10-dimethyl-9-(cis-1-methyl-1-propenyl)phenanthrenium ion generated by reaction of 1,2,2a,10b-tetramethyl-2a,10b-dihydrocyclobuta[l]phenanthrene with HSO3F below -100degreesC undergoes very fast (DeltaG(not equal) = 22 kJ/mol at -120degreesC) degenerate 1,2-shift of the dimethylvinyl group.
Библиографическая ссылка:
Bushmelev V.
, Genaev A.
, Shubin V.
Degenerate rearrangement of long-lived 9,10-dimethyl-9-(cis-1-methyl-1-propenyl)phenanthrenium ion: 1,2-shift of the dimethylvinyl group
Russian Journal of Organic Chemistry. 2004. V.40. N7. P.966-972. DOI: 10.1023/B:RUJO.0000045186.11978.a5 WOS Scopus РИНЦ OpenAlex
Degenerate rearrangement of long-lived 9,10-dimethyl-9-(cis-1-methyl-1-propenyl)phenanthrenium ion: 1,2-shift of the dimethylvinyl group
Russian Journal of Organic Chemistry. 2004. V.40. N7. P.966-972. DOI: 10.1023/B:RUJO.0000045186.11978.a5 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 июл. 2004 г. |
Идентификаторы БД:
| Web of science: | WOS:000224997000010 |
| Scopus: | 2-s2.0-6344222107 |
| РИНЦ: | 14576428 |
| OpenAlex: | W2040546095 |