Abstract: According to the X-ray diffraction data, the cationic fragment in 1-amino-1,10-phenanthrolinium mesitylenesulfonate is a unidentate n-complex whose asymmetric structure is retained in solution. Quantum-chemical calculations by the AMI method and ab initio (6-31G 6-31G*, MP2/6-31G) give geometric parameters of the cation, which are similar to those determined experimentally. No dynamic processes involving intra- or intermolecular transfer of the NH2 group was observed up to 100degreesC by NMR spectroscopy. 1-Amino-1,10-phenanthrolinium cation does not react with 4-methylpyridine and 4-methyl-1,10-phenanthroline with transfer of the amino group, and it fails to react with mesitylene and anthracene at elevated temperature.

Cite: Andreev R. , Borodkin G. , Gatilov Y. , Shakirov M. , Shubin V.
Structure and reactivity of the 1,10-phenanthroline complex with nitrenium cation
Russian Journal of Organic Chemistry. 2004. V.40. N4. P.567-574. DOI: 10.1023/B:RUJO.0000036081.51473.c0 WOS Scopus РИНЦ OpenAlex

Original: Андреев Р.В. , Бородкин Г.И. , Гатилов Ю.В. , Шакиров М.М. , Шубин В.Г.
Строение и реакционная способность комплекса 1,10-фенантролина с нитрений-катионом
Журнал органической химии (RUSS J ORG CHEM+). 2004. Т.40. №4. С.595-602. РИНЦ

Dates:

Published print:

Apr 1, 2004

Identifiers:

Web of science:	WOS:000222560400021
Scopus:	2-s2.0-4043089748
Elibrary:	14462973
OpenAlex:	W2045953930

Citing:

DB	Citing
Web of science	7
Scopus	6
OpenAlex	6

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