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C-Alkylation of nitroso chlorides with diethyl malonate: The X-ray structure of diethyl (+/-)-(1R*,2S*,5R*)-2-{3(E)-hydroxyimino-2,6,6-trimethylbicyclo[3.1.1]-hept-2-yl}malonate Full article

Journal Mendeleev Communications
ISSN: 0959-9436
Output data Year: 2004, Volume: 14, Number: 1, Pages: 18-20 Pages count : DOI: 10.1070/MC2004v014n01ABEH001799
Authors Bizjaev SN , Rybalova TV , Gatilov YV , Tkachev AV
Affiliations
1 (Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia
2 (Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Abstract: The reactions of the nitroso chlorides of methylcyclohexene, limonene, 3-carene, and a-pinene with an excess of diethyl malonate in the presence of anhydrous K2CO3 at room temperature resulted in the C-alkylation and formation of a-substituted oximes with a diethyl malonate moiety in 20-90% yields.
Cite: Bizjaev S. , Rybalova T. , Gatilov Y. , Tkachev A.
C-Alkylation of nitroso chlorides with diethyl malonate: The X-ray structure of diethyl (+/-)-(1R*,2S*,5R*)-2-{3(E)-hydroxyimino-2,6,6-trimethylbicyclo[3.1.1]-hept-2-yl}malonate
Mendeleev Communications. 2004. V.14. N1. P.18-20. DOI: 10.1070/MC2004v014n01ABEH001799 WOS Scopus РИНЦ OpenAlex
Dates:
Published print: Jan 1, 2004
Identifiers:
Web of science: WOS:000220899600008
Scopus: 2-s2.0-1942425538
Elibrary: 13459267
OpenAlex: W2175170528
Citing:
DB Citing
Web of science 10
Scopus 9
Elibrary 10
OpenAlex 10
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