The stereospecific substitution of the xenon atom in cis-perfluoroalk-1-enylxenon(II) salts by hydrogen, halogens, and the phenyl group Full article
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Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 |
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| Output data | Year: 2004, Volume: 630, Number: 7, Pages: 1022-1024 Pages count : DOI: 10.1002/zaac.200400056 | ||||
| Tags | noble gas chemistry; xenon-carbon compounds; perfluoroalk-1-enylation reactions; stereochemistry | ||||
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Abstract:
The substitution of the xenon atom in reactions of [cis-CnF2+1CF=CFXe][Y] salts with benzene, iodide, and bromide anions in propionitrile solution by the phenyl group, or iodine, and bromine atoms, respectively, occurred stereospecifically. When a propionitrile solution of [cis-C2F5CF=CFXe][AsF6] was kept at -40 degreesC without an additional reactant, the fluoroalkene cis-C2F5CF=CFH was the only isomer obtained.
Cite:
Frohn H.
, Bardin V.
The stereospecific substitution of the xenon atom in cis-perfluoroalk-1-enylxenon(II) salts by hydrogen, halogens, and the phenyl group
Zeitschrift fur Anorganische und Allgemeine Chemie. 2004. V.630. N7. P.1022-1024. DOI: 10.1002/zaac.200400056 WOS Scopus РИНЦ OpenAlex
The stereospecific substitution of the xenon atom in cis-perfluoroalk-1-enylxenon(II) salts by hydrogen, halogens, and the phenyl group
Zeitschrift fur Anorganische und Allgemeine Chemie. 2004. V.630. N7. P.1022-1024. DOI: 10.1002/zaac.200400056 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Jul 1, 2004 |
Identifiers:
| Web of science: | WOS:000222967800011 |
| Scopus: | 2-s2.0-4644252703 |
| Elibrary: | 13461676 |
| OpenAlex: | W2150130117 |