(Fluoroorgano)fluoroboranes and -borates. 11 - The electrochemical oxidation of polyfluorophenyltrifluoroborate anions in acetonitrile Full article
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Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 |
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| Output data | Year: 2004, Volume: 630, Number: 8-9, Pages: 1253-1257 Pages count : 5 DOI: 10.1002/zaac.200400017 | ||||
| Tags | arylfluoroborates; electrochemical oxidation; cyclic voltammetry; one-electron transfer process | ||||
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Abstract:
The potentials for the electrochemical oxidation of potassium polyfluorophenyltrifluoroborate salts K[C6H5-nFnBF3] (n = 0-5) were measured by cyclic voltammetry in CH3CN. In all cases the first oxidation peak corresponded to irreversible processes at the Pt electrode. The good correlation between the observed first oxidation peak potential values, E-p(1), and the calculated (RHF, MNDO approximation) vertical ionisation potentials of the polyfluorophenyltrifluoroborate anions, [C6H5-nFnBF3](-), indicates an one-electron step as first step of the oxidation. The formation of C6F5H and of the adduct (BF3NCCH3)-N-. in the potential controlled electrolysis of K[C6F5BF3] in CH3CN is in agreement with this assumption.
Cite:
Shundrin L.
, Bardin V.
, Frohn H.
(Fluoroorgano)fluoroboranes and -borates. 11 - The electrochemical oxidation of polyfluorophenyltrifluoroborate anions in acetonitrile
Zeitschrift fur Anorganische und Allgemeine Chemie. 2004. V.630. N8-9. P.1253-1257. DOI: 10.1002/zaac.200400017 WOS Scopus РИНЦ OpenAlex
(Fluoroorgano)fluoroboranes and -borates. 11 - The electrochemical oxidation of polyfluorophenyltrifluoroborate anions in acetonitrile
Zeitschrift fur Anorganische und Allgemeine Chemie. 2004. V.630. N8-9. P.1253-1257. DOI: 10.1002/zaac.200400017 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Aug 1, 2004 |
Identifiers:
| Web of science: | WOS:000223426500017 |
| Scopus: | 2-s2.0-4644247964 |
| Elibrary: | 13464750 |
| OpenAlex: | W2135364782 |