Preparation of 1-X-2,2-difluoroethenylxenon(II) tetrafluoroborates [CF2=CXXe][BF4] Full article
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Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 |
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| Output data | Year: 2003, Volume: 629, Number: 14, Pages: 2465-2469 Pages count : DOI: 10.1002/zaac.200300224 | ||||
| Tags | noble gas chemistry; xenon-carbon compounds; polyfluoroalkenylboranes; xenodeborylation; polyfluoroalkylborate anions; NMR spectroscopy | ||||
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Abstract:
The new type of alkenylxenon(II) salts [CF2=CXXe] [BF4] (X = H, Cl, CF3) was prepared by reacting the corresponding alkenyldifluoroboranes CF2 = CXBF2 with XeF2 in 1,1,1,3,3-pentafluoropropane (PFP) at -60 degreesC. The alkenylxenon(II) salts were characterised by multinuclear NMR spectroscopy. The influence of the substituent X at C-1 on the stability of alkenylxenon(II) salts is discussed. Additionally the preparation of the potassium alkenyl-trifluoroborate salts K [CF2=CXBF3] and their transformation into the boranes CF2=CXBF2 by fluoride abstraction in PFP is reported.
Cite:
Frohn H.
, Bardin V.
Preparation of 1-X-2,2-difluoroethenylxenon(II) tetrafluoroborates [CF2=CXXe][BF4]
Zeitschrift fur Anorganische und Allgemeine Chemie. 2003. V.629. N14. P.2465-2469. DOI: 10.1002/zaac.200300224 WOS Scopus РИНЦ OpenAlex
Preparation of 1-X-2,2-difluoroethenylxenon(II) tetrafluoroborates [CF2=CXXe][BF4]
Zeitschrift fur Anorganische und Allgemeine Chemie. 2003. V.629. N14. P.2465-2469. DOI: 10.1002/zaac.200300224 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Dec 1, 2003 |
Identifiers:
| Web of science: | WOS:000188203600011 |
| Scopus: | 2-s2.0-0347090478 |
| Elibrary: | 13437556 |
| OpenAlex: | W1974191764 |