Synthesis, structure, and properties of nickel(II) and cobalt(II) coordination compounds with optically active diaminodioxime (H2L) derived from 3-carene. Molecular and crystal structures of the [Ni(H2L)(NO3)]NO3 and [Ni(HL)]ClO4 center dot H2O complexes Full article
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284 |
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| Output data | Year: 2003, Volume: 29, Number: 11, Pages: 795-804 Pages count : 10 DOI: 10.1023/B:RUCO.0000003437.79753.d6 | ||||
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Abstract:
Nickel(II) and cobalt(II) complexes with optically active diaminodioxime (H2L, the derivative of 3-carene) of the compositions [Ni(H2L)NO3]NO3 (1), Ni(H2L)Cl-2 (II), [Ni(HL)]ClO4 (.) H2O (III), and Co(H2L)Cl-2 (IV), were synthesized. According to X-ray diffraction data, the structures of the paramagnetic compound I and diamagnetic complex III are ionic. In the cation of I, the distorted NiN4O2 octahedron is formed by the N atoms of the tetradentate cyclic ligand (H,L molecule) and by the O atoms of NO3- anion functioning as bidentate cyclic ligands. In the cation of III, the NiN4 coordination unit is a distorted square formed upon coordination of the tetradentate cyclic ligand, HL- anion. The data of magnetochemistry and UV-Vis, IR, and Raman spectroscopy suggest that paramagnetic complexes H and IV contain a distorted octahedral polyhedron MCl2N4 (M = Ni, Co).
Cite:
Larionov S.
, Myachina L.
, Glinskaya L.
, Klevtsova R.
, Sheludyakova L.
, Tkachev A.
, Bizyaev S.
Synthesis, structure, and properties of nickel(II) and cobalt(II) coordination compounds with optically active diaminodioxime (H2L) derived from 3-carene. Molecular and crystal structures of the [Ni(H2L)(NO3)]NO3 and [Ni(HL)]ClO4 center dot H2O complexes
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2003. V.29. N11. P.795-804. DOI: 10.1023/B:RUCO.0000003437.79753.d6 WOS Scopus РИНЦ OpenAlex
Synthesis, structure, and properties of nickel(II) and cobalt(II) coordination compounds with optically active diaminodioxime (H2L) derived from 3-carene. Molecular and crystal structures of the [Ni(H2L)(NO3)]NO3 and [Ni(HL)]ClO4 center dot H2O complexes
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2003. V.29. N11. P.795-804. DOI: 10.1023/B:RUCO.0000003437.79753.d6 WOS Scopus РИНЦ OpenAlex
Original:
Ларионов С.В.
, Мячина Л.И.
, Глинская Л.А.
, Клевцова Р.Ф.
, Шелудякова Л.А.
, Ткачев А.В.
, Бизяев С.Н.
Синтез, строение и свойства координационных соединений никеля(ii) и кобальта(ii) с оптически активным диаминодиоксимом (h 2l) -производным 3-карена. молекулярные и кристаллические структуры комплексов [Ni(H2L)(NO3)]NO3 и [Ni(HL)]ClO4 • H 2O
Координационная химия (RUSS J COORD CHEM+). 2003. Т.29. №11. С.857. РИНЦ
Синтез, строение и свойства координационных соединений никеля(ii) и кобальта(ii) с оптически активным диаминодиоксимом (h 2l) -производным 3-карена. молекулярные и кристаллические структуры комплексов [Ni(H2L)(NO3)]NO3 и [Ni(HL)]ClO4 • H 2O
Координационная химия (RUSS J COORD CHEM+). 2003. Т.29. №11. С.857. РИНЦ
Dates:
| Published print: | Nov 1, 2003 |
Identifiers:
| Web of science: | WOS:000186826400006 |
| Scopus: | 2-s2.0-3543084596 |
| Elibrary: | 13437982 |
| OpenAlex: | W2020536331 |