Polyfluoroorganoboron oxygen compounds, part 3. The palladium-catalysed cross-coupling reaction of lithium polyfluorophenyltrimethoxyborates with 4-fluoroiodobenzene Full article
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Output data | Year: 2003, Volume: 122, Number: 2, Pages: 195-199 Pages count : 5 DOI: 10.1016/S0022-1139(03)00088-5 | ||||
| Tags | polyfluoroarylborates; methoxyborates; cross-coupling; polyfluorobiphenyls; palladium catalysis; silver oxide | ||||
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Abstract:
Li[C6F5B(OMe)(3)]. Li[C6HF4B(OMe)(3)] (all three isomers) and Li[3,4,5-C6H2F3B(OMe)(3)] are the first examples of polyfluorophenyltrimethoxyborate salts which have been applied as reagents to Pd-catalysed cross-coupling reactions. A series of polyfluorinated biphenyls C6H5-nFn-C6H4F-4' were obtained from Li[C6H5-nFnB(OMe)(3)] and the model substrate 4-FC6H4I in the presence of Pd catalysts. The influence of the number and the position of fluorine atoms in the polyfluorophenyltrimetboxyborate salts on the reactivity in the coupling reaction was elucidated. (C) 2003 Elsevier Science B.V. All rights reserved.
Cite:
Frohn H.
, Adonin N.
, Bardin V.
, Starichenko V.
Polyfluoroorganoboron oxygen compounds, part 3. The palladium-catalysed cross-coupling reaction of lithium polyfluorophenyltrimethoxyborates with 4-fluoroiodobenzene
Journal of Fluorine Chemistry. 2003. V.122. N2. P.195-199. DOI: 10.1016/S0022-1139(03)00088-5 WOS Scopus РИНЦ OpenAlex
Polyfluoroorganoboron oxygen compounds, part 3. The palladium-catalysed cross-coupling reaction of lithium polyfluorophenyltrimethoxyborates with 4-fluoroiodobenzene
Journal of Fluorine Chemistry. 2003. V.122. N2. P.195-199. DOI: 10.1016/S0022-1139(03)00088-5 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Aug 1, 2003 |
Identifiers:
| Web of science: | WOS:000184654600009 |
| Scopus: | 2-s2.0-0041802882 |
| Elibrary: | 13419558 |
| OpenAlex: | W1972998333 |