Study of chiral beta-enaminones prepared from pyrrolidine, cytisine, salsoline and 2-amino-1-(4-nitrophenyl)propane-1,3-diol: resolution of salsoline via diastereomeric modified carane-type beta-enaminones Full article
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Tetrahedron Asymmetry
ISSN: 0957-4166 |
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| Output data | Year: 2003, Volume: 14, Number: 2, Article number : PII S0957-4166(02)00781-4, Pages count : DOI: 10.1016/S0957-4166(02)00781-4 | ||||
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Abstract:
A series of novel optically active beta-enaminones have been prepared regio- and stereoselectively from primary and secondary amines (pyrrolidine, cytisine salsoline and 2-amino-l-(4-nitrophenyl)propane-1,3-diol) and (+)-3-carene-derived beta-chlorovinyl ketone. Resolution of the isoquinoline alkaloid salsoline has been demonstrated as well as isolation of a single diastereomeric adduct from racemic 2-amino-1-(4-nitrophenyl)propane-1,3-diol. (C) 2003 Elsevier Science Ltd. All rights reserved.
Cite:
Popov S.
, Gatilov Y.
, Rybalova T.
, Tkachev A.
Study of chiral beta-enaminones prepared from pyrrolidine, cytisine, salsoline and 2-amino-1-(4-nitrophenyl)propane-1,3-diol: resolution of salsoline via diastereomeric modified carane-type beta-enaminones
Tetrahedron Asymmetry. 2003. V.14. N2. PII S0957-4166(02)00781-4 . DOI: 10.1016/S0957-4166(02)00781-4 WOS Scopus OpenAlex
Study of chiral beta-enaminones prepared from pyrrolidine, cytisine, salsoline and 2-amino-1-(4-nitrophenyl)propane-1,3-diol: resolution of salsoline via diastereomeric modified carane-type beta-enaminones
Tetrahedron Asymmetry. 2003. V.14. N2. PII S0957-4166(02)00781-4 . DOI: 10.1016/S0957-4166(02)00781-4 WOS Scopus OpenAlex
Dates:
| Published print: | Jan 1, 2003 |
Identifiers:
| Web of science: | WOS:000180696700011 |
| Scopus: | 2-s2.0-0037449685 |
| OpenAlex: | W2001101863 |