Molecular complexes of octafluoronaphthalene with acyclic and heterocyclic sulfur-nitrogen compounds Full article
| Journal |
Journal of Fluorine Chemistry
ISSN: 0022-1139 |
||||
|---|---|---|---|---|---|
| Output data | Year: 2002, Volume: 116, Number: 2, Article number : PII S0022-1139(02)00127-6, Pages count : 8 DOI: 10.1016/S0022-1139(02)00127-6 | ||||
| Tags | octafluoronaphthalene; sulfur-nitrogen compounds; molecular complexes; pi-stacking interactions; X-ray structure determination | ||||
| Authors |
|
||||
| Affiliations |
|
Abstract:
Mismatched molecular 1:1 complexes were prepared from C10F8 and sulfur diimides Ar-N=S=N-Ar 1 and Ar-N=S=N-SiMe3 2, 3 (1, 2: Ar = 2,6-dimethylphenyl; 3: Ar = phenyl). In the case of 2, the complexation is accompanied by the unexpected cyclization of 2 into 7-methyl-2,1-benzisothiazole 4. The X-ray molecular structures of C10F8.1, C10F8.3 and C10F8 are presented; in C10F8.4 the 7-methyl-2,1-benzisothiazole 4 is highly disordered. The complexes provide very rare examples of markedly bent (C10F8.1), polyheteroatom (C10F8.3) and heterocyclic (C10F8.4) molecules involved in non-covalent arene-polyfluoroarene pi-stacking interactions. (C) 2002 Elsevier Science B.V. All rights reserved.
Cite:
Bagryanskaya I.
, Gatilova Y.
, Lork E.
, Mews R.
, Shakirov M.
, Watson P.
, Zibarev A.
Molecular complexes of octafluoronaphthalene with acyclic and heterocyclic sulfur-nitrogen compounds
Journal of Fluorine Chemistry. 2002. V.116. N2. PII S0022-1139(02)00127-6 :1-8. DOI: 10.1016/S0022-1139(02)00127-6 WOS Scopus РИНЦ OpenAlex
Molecular complexes of octafluoronaphthalene with acyclic and heterocyclic sulfur-nitrogen compounds
Journal of Fluorine Chemistry. 2002. V.116. N2. PII S0022-1139(02)00127-6 :1-8. DOI: 10.1016/S0022-1139(02)00127-6 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Aug 1, 2002 |
Identifiers:
| Web of science: | WOS:000178064200009 |
| Scopus: | 2-s2.0-0037189826 |
| Elibrary: | 13391298 |
| OpenAlex: | W2036463175 |