Induced alkene reactions with sulfur dichloride. System sulfur dichloride-dimethyl sulfide as a reagent for polysulfonation and conjugate chlorination of alkenes

Induced alkene reactions with sulfur dichloride. System sulfur dichloride-dimethyl sulfide as a reagent for polysulfonation and conjugate chlorination of alkenes Научная публикация

Журнал

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Вых. Данные

Год: 2002, Том: 38, Номер: 8, Страницы: 1105-1112 Страниц : 8 DOI: 10.1023/A:1020933005986

Авторы

Bodrikov I.V. ¹ , Sazhin A.A. ¹ , Shebelova I.Yu. ¹ , Subbotin A.Yu. ¹ , Rybalova T..V. ² , Gatilov Yu.V. ² , Barkhash V.A. ²

Организации

1	(Данные Web of science) Nizhegorodskii State Tech Univ, Nizhnii Novgorod 603024, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Div, Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

In reaction of unsaturated compounds with sulfur dichloride in the presence of dimethyl sulfide radically new induced directions are realized: the reagent is involved as dimer or trimer (formation of di- and trisulfides). Alongside this process a conjugate chlorination occurred with participation of external nucleophiles, dimethyl sulfide and acetonitrile, furnishing sulfonium chlorides and N-substituted acetamides respectively. The relative importance of these alternative reactions depends on solvent, alkene structure, and order of reagents addition.

Bodrikov I.V. , Sazhin A.A. , Shebelova I.Y. , Subbotin A.Y. , Rybalova T.V. , Gatilov Y.V. , Barkhash V.A.
Induced alkene reactions with sulfur dichloride. System sulfur dichloride-dimethyl sulfide as a reagent for polysulfonation and conjugate chlorination of alkenes
Russian Journal of Organic Chemistry. 2002. V.38. N8. P.1105-1112. DOI: 10.1023/A:1020933005986 WOS Scopus РИНЦ OpenAlex

Web of science:	WOS:000179993700006
Scopus:	2-s2.0-0036410661
РИНЦ:	13395593
OpenAlex:	W2949920823

БД	Цитирований
Web of science	1
Scopus	1
РИНЦ	2
OpenAlex	1