Pentafluorophenylation of perfluorinated benzocyclobutene, indan, and tetralin by reaction with pentafluorobenzene in SbF5 Научная публикация
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Вых. Данные | Год: 2002, Том: 38, Номер: 8, Страницы: 1158-1165 Страниц : 8 DOI: 10.1023/A:1020901526459 | ||
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Реферат:
The reactivity of perfluorinated benzocyclobutene, indan, and tetralin in reaction with pentafluorobenzene in SbF5 medium, and also the relative stability of generated therewith perfluoro-1-phenyl-benzocycloalkenyl cations decrease with increasing alicyclic fragment in the benzocycloalkene. Treating the solutions of salts of the above cations with anhydrous HF results in the corresponding perfluoro-1-phenylbenzocycloalkenes, and the hydrolysis of salts furnishes their 1-hydroxy derivatives. In a reaction of 1-hydroxyperfluoro-1-phenylbenzocyclobutene, -indan, and -tetralin with SOCl2 the hydroxy group is replaced by chlorine. Besides with indan and tetralin derivatives form respectively 7-pentafluorophenyl-octafluoro-3-chlorobicyclo[4.3.0]hepta- 1,4,6-triene and 7-pentafluorophenyldecafluoro-3-chlorobicyclo[4.4.0]octa-1,4,6-triene.
Библиографическая ссылка:
Karpov V.M.
, Mezhenkova T.V.
, Platonov V.E.
, Sinyakov V.R.
, Shchegoleva L.N.
Pentafluorophenylation of perfluorinated benzocyclobutene, indan, and tetralin by reaction with pentafluorobenzene in SbF5
Russian Journal of Organic Chemistry. 2002. V.38. N8. P.1158-1165. DOI: 10.1023/A:1020901526459 WOS Scopus РИНЦ OpenAlex
Pentafluorophenylation of perfluorinated benzocyclobutene, indan, and tetralin by reaction with pentafluorobenzene in SbF5
Russian Journal of Organic Chemistry. 2002. V.38. N8. P.1158-1165. DOI: 10.1023/A:1020901526459 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000179993700015 |
| Scopus: | 2-s2.0-0036412387 |
| РИНЦ: | 13415453 |
| OpenAlex: | W2950418988 |