Catalytic and noncatalytic ammonolysis of polyfluorinated 1,3-dichlorobenzenes Научная публикация
| Журнал |
Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Вых. Данные | Год: 2002, Том: 38, Номер: 7, Страницы: 1023-1029 Страниц : 7 DOI: 10.1023/A:1020861831098 | ||
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Реферат:
Reactions of 1,3-dichlorotetrafluorobenzene and 1,3-dichloro-2,4,6-trifluorobenzene with aqueous ammonia in the presence and in the absence of copper(I) salt lead to fluorine replacement by amino group in the para and ortho positions with respect to the chlorine atom. Ammonolysis of the resulting chloropoly-fluoroanilines in the absence of a catalyst involves replacement of fluorine atom in the meta position with respect to the amino group. In the presence of copper(I) salt, catalytic aminodechlorination occurs at the para and ortho positions with respect to the amino group introduced in the first stage.
Библиографическая ссылка:
Selivanova G.A.
, Pokrovskii L.M.
, Shteingarts V.D.
Catalytic and noncatalytic ammonolysis of polyfluorinated 1,3-dichlorobenzenes
Russian Journal of Organic Chemistry. 2002. V.38. N7. P.1023-1029. DOI: 10.1023/A:1020861831098 WOS Scopus РИНЦ OpenAlex
Catalytic and noncatalytic ammonolysis of polyfluorinated 1,3-dichlorobenzenes
Russian Journal of Organic Chemistry. 2002. V.38. N7. P.1023-1029. DOI: 10.1023/A:1020861831098 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000179627200013 |
| Scopus: | 2-s2.0-0036413796 |
| РИНЦ: | 43360804 |
| OpenAlex: | W2953264167 |