The first N-alkyl-N '-polyfluorohetaryl sulfur diimide Full article
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Output data | Year: 2002, Volume: 115, Number: 2, Article number : PII S0022-1139(02)00047-7, Pages count : 4 DOI: 10.1016/S0022-1139(02)00047-7 | ||||
| Tags | alkylthiazylamide; fluoroelectrophiles; sulfur diimides; polyfluorinated; X-ray structure determination | ||||
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Abstract:
The first Alk-N=S=N-Het(F) sulfur diimide 6 (Alk = adamant-1-yl, Het(F) = 2,3,5,6-tetrafluoropyrid-4-yl) was prepared by trapping of the corresponding alkylthiazylamide [AlkNSN](-) 3 with pentafluoropyridine, followed by X-ray structural characterization. For 6, the Z,E configuration was found. From the reaction of 3 with octafluoronaphthalene, hexafluorinated naphthothiadiazole 7 was isolated along with the parent AlkNH(2). (C) 2002 Elsevier Science B.V. All rights reserved.
Cite:
Lork E.
, Mews R.
, Shakirov M.
, Watson P.
, Zibarev A.
The first N-alkyl-N '-polyfluorohetaryl sulfur diimide
Journal of Fluorine Chemistry. 2002. V.115. N2. PII S0022-1139(02)00047-7 :1-4. DOI: 10.1016/S0022-1139(02)00047-7 WOS Scopus РИНЦ OpenAlex
The first N-alkyl-N '-polyfluorohetaryl sulfur diimide
Journal of Fluorine Chemistry. 2002. V.115. N2. PII S0022-1139(02)00047-7 :1-4. DOI: 10.1016/S0022-1139(02)00047-7 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Jun 1, 2002 |
Identifiers:
| Web of science: | WOS:000176607900011 |
| Scopus: | 2-s2.0-0037188804 |
| Elibrary: | 13413832 |
| OpenAlex: | W2174948923 |