Reductive activation of arenes: XV. Anionic products of m-tolynitrile reduction with sodium in liquid ammonia, and their alkylation Научная публикация
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Вых. Данные | Год: 2002, Том: 38, Номер: 6, Страницы: 823-829 Страниц : 7 DOI: 10.1023/A:1020387003972 | ||
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Реферат:
From results of oxidation, protonation, and alkylation of the products arising in one- or two-electron reduction of m-tolunitrile with sodium in liquid ammonia followed a conclusion that these products are respectively anion-radical of the compound and 3-methyl-1-cyano-2,5-cyclohexadienyl anion. The reaction of both reduction products with alkyl halides gives rise to compounds of ipso-alkylation with respect to cyano group: the corresponding alkyltoluenes and 1-alkyl-3-methyl-1-cyclohexadienes. The ratio of these products depends on the structure of alkyl halide. The possibility to prepare selectively m-alkyltoluenes by reaction of the product of two-electron reduction of m-tolunitrile with alkyl halides was demonstrated.
Библиографическая ссылка:
Vaganova T.
, Starokon' E.
, Shteingarts V.
Reductive activation of arenes: XV. Anionic products of m-tolynitrile reduction with sodium in liquid ammonia, and their alkylation
Russian Journal of Organic Chemistry. 2002. V.38. N6. P.823-829. DOI: 10.1023/A:1020387003972 WOS Scopus РИНЦ OpenAlex
Reductive activation of arenes: XV. Anionic products of m-tolynitrile reduction with sodium in liquid ammonia, and their alkylation
Russian Journal of Organic Chemistry. 2002. V.38. N6. P.823-829. DOI: 10.1023/A:1020387003972 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000177926900008 |
| Scopus: | 2-s2.0-0036389215 |
| РИНЦ: | 13405022 |
| OpenAlex: | W2950027433 |