Reductive activation of arenes: XIV. Effect of medium on the products ratio in the alkylation of nitrobenzene radical anion sodium salt Full article
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Output data | Year: 2001, Volume: 37, Number: 12, Pages: 1719-1722 Pages count : 4 DOI: 10.1023/A:1013969901048 | ||
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Abstract:
The product of nitrobenzene reduction by 1 equiv of sodium reacted with tert-butyl iodide in liquid ammonia and its mixtures with tetrahydrofuran and hexamethylphosphoramide to afford a mixture of compounds alkylated either by the functional group (N-alkylation) or at the benzene ring (C-alkylation). The ratio of N- and C-alkylation products decreases in the solvents series NH3-THF (5.7) > NH3 (1.0) > NH3-HMPA (0.6).
Cite:
Selivanov B.A.
, Shteingarts V.D.
Reductive activation of arenes: XIV. Effect of medium on the products ratio in the alkylation of nitrobenzene radical anion sodium salt
Russian Journal of Organic Chemistry. 2001. V.37. N12. P.1719-1722. DOI: 10.1023/A:1013969901048 WOS Scopus РИНЦ OpenAlex
Reductive activation of arenes: XIV. Effect of medium on the products ratio in the alkylation of nitrobenzene radical anion sodium salt
Russian Journal of Organic Chemistry. 2001. V.37. N12. P.1719-1722. DOI: 10.1023/A:1013969901048 WOS Scopus РИНЦ OpenAlex
Identifiers:
| Web of science: | WOS:000174580600010 |
| Scopus: | 2-s2.0-0035528730 |
| Elibrary: | 13386586 |
| OpenAlex: | W267018193 |