0D to 3D Coordination Assemblies Engineered on Silver(I) Salts and 2-(Alkylsulfanyl)azine Ligands: Crystal Structures, Dual Luminescence, and Cytotoxic Activity

0D to 3D Coordination Assemblies Engineered on Silver(I) Salts and 2-(Alkylsulfanyl)azine Ligands: Crystal Structures, Dual Luminescence, and Cytotoxic Activity Full article

Journal

European Journal of Inorganic Chemistry
ISSN: 1434-1948 , E-ISSN: 1099-0682

Output data

Year: 2020, Volume: 2020, Number: 17, Pages: 1635-1644 Pages count : 10 DOI: 10.1002/ejic.202000109

Tags

Sulfide ligands; Silver; Coordination polymers; Dual luminescence; Cytotoxicity

Authors

Rogovoy Maxim I. ¹ , Frolova Tatiana S. ^2,3 , Samsonenko Denis G. ¹ , Berezin Alexey S. ¹ , Bagryanskaya Irina Yu. ⁴ , Nedolya Nina A. ⁵ , Tarasova Olga A. ⁵ , Fedin Vladimir P. ¹ , Artem'ev Alexander V. ¹

Affiliations

1	(Данные Web of science) RAS, SB, Nikolaev Inst Inorgan Chem, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia
3	(Данные Web of science) RAS, SB, Inst Cytol & Genet, 10 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
4	(Данные Web of science) RAS, SB, NN Vorozhtsov Novosibirsk Inst Organ Chem, 9 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
5	(Данные Web of science) RAS, SB, AE Favorsky Irkutsk Inst Chem, 1 Favorsky St, Irkutsk 664033, Russia

The potential of 2-(alkylsulfanyl)azine ligands for crystal engineering of functional Ag-(I) complexes has been firstly demonstrated. The reaction of AgNO3, AgClO4 and AgOTf with 2-(alkylsulfanyl)pyridines, -pyrimidines, and -quinolines gives a series of new Ag-(I) compounds that range from mono- and dinuclear complexes to chain (1D), layered (2D) and framework (3D) coordination polymers (CPs). 2-(Alkylsulfanyl)pyridines and -pyrimidines, depending on the reaction conditions, are assembled either into molecular complexes or CPs, while 2-(alkylsulfanyl)quinolines afford dinuclear complexes exclusively. The most of compounds engineered feature site-specific interactions such as Ag center dot center dot center dot Ag, Ag center dot center dot center dot O, and Ag center dot center dot center dot S ones. The 2-(methylsulfanyl)quinoline (2-MeSQn) complex, [Ag-2(2-MeSQn)(2)(NO3)(2)], displays room temperature intraligand (IL) phosphorescence, while the 2-(methylsulfanyl)pyridine-derived CPs emit dual luminescence expressed by IL fluorescence and phosphorescence. Moreover, cytotoxic activity of the compounds synthesized has been evaluated against hTERT lung fibroblasts, HeLa, MCF7, HepG2 and A549 cancer cells.

Rogovoy M.I. , Frolova T.S. , Samsonenko D.G. , Berezin A.S. , Bagryanskaya I.Y. , Nedolya N.A. , Tarasova O.A. , Fedin V.P. , Artem'ev A.V.
0D to 3D Coordination Assemblies Engineered on Silver(I) Salts and 2-(Alkylsulfanyl)azine Ligands: Crystal Structures, Dual Luminescence, and Cytotoxic Activity
European Journal of Inorganic Chemistry. 2020. V.2020. N17. P.1635-1644. DOI: 10.1002/ejic.202000109 WOS Scopus РИНЦ OpenAlex

Published online:	Apr 21, 2020
Published print:	May 10, 2020

Web of science:	WOS:000527685600001
Scopus:	2-s2.0-85083663579
Elibrary:	43284870
OpenAlex:	W3013810754

DB	Citing
Web of science	31
Scopus	26
Elibrary	29
OpenAlex	31