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(Fluoroorgano)fluoroboranes and -fluoroborates. 2. Synthesis and spectroscopic characterization of potassium polyfluoroalken-1-yltrifluoroborates Full article

Journal Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313
Output data Year: 2001, Volume: 627, Number: 11, Pages: 2499-2505 Pages count : DOI: 10.1002/1521-3749(200111)627:11<2499::AID-ZAAC2499>3.0.CO;2-Z
Tags borates; polyfluoroalken-1-yl; NMR spectroscopy
Authors Frohn HL , Bardin VV
Affiliations
1 (Данные Web of science) Univ Duisburg Gesamthsch, Fachgebiet Anorgan Chem, D-47048 Duisburg, Germany
2 (Данные Web of science) NN Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

Abstract: (T)he potassium fluoroborates K[RCF=CFBF3] (R = F, Cl (cis-/trans-mixture), trans-C4F9, cis-C2F5, cisC(6)F(13), trans-C4H9, trans-C6H5) were prepared by fluoridation (methoxide-fluoride substitution with K[HF2]) of RCF=CFB(OMe)(2) and Li[RCF=CFB(OMe)(3)] which were obtained from RCF=CFLi and B(OMC)(3). The K[RCF=CFBF3] salts were characterized by their H-1, B-11, F-19 NMR and IR spectra.
Cite: Frohn H. , Bardin V.
(Fluoroorgano)fluoroboranes and -fluoroborates. 2. Synthesis and spectroscopic characterization of potassium polyfluoroalken-1-yltrifluoroborates
Zeitschrift fur Anorganische und Allgemeine Chemie. 2001. V.627. N11. P.2499-2505. DOI: 10.1002/1521-3749(200111)627:11<2499::AID-ZAAC2499>3.0.CO;2-Z WOS Scopus РИНЦ OpenAlex
Dates:
Published print: Nov 1, 2001
Identifiers:
Web of science: WOS:000172197000011
Scopus: 2-s2.0-0035646626
Elibrary: 13386728
OpenAlex: W1978860933
Citing:
DB Citing
Web of science 41
Scopus 40
Elibrary 47
OpenAlex 38
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