Direct C-nitration of cyclic alpha,beta-unsaturated oximes under the action of sodium nitrite and acetic acid in methanol Научная публикация
| Журнал |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Вых. Данные | Год: 2001, Том: 50, Номер: 8, Страницы: 1410-1418 Страниц : 9 DOI: 10.1023/A:1012785007135 | ||||||
| Ключевые слова | alpha,beta-unsaturated oximes; conjugated ketones; nitrosation; C-nitration; deoximation; nitroalkenes; circular dichroism | ||||||
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Реферат:
Using a number of cyclic alpha,beta-unsaturated oximes of the terpene series and sonic Simplest model compounds as examples, unsaturated oximes bearing a hydrogen atom it the beta-carbon atom were demonstrated to be converted into beta-hydroxyiminonitroalkenes under the action of sodium nitrite and acetic acid in methanol. In the case of the introduction of an alkyl substituent at the terminal carbon atom of the diene C=C-C=NOH fragment, the reaction performed under the same conditions gave rise exclusively to conjugated ketone (a deoximation product).
Библиографическая ссылка:
Chibiryaev A.M.
, Denisov A.Y.
, Pyshnyi D.V.
, Tkachev A.V.
Direct C-nitration of cyclic alpha,beta-unsaturated oximes under the action of sodium nitrite and acetic acid in methanol
Russian Chemical Bulletin. 2001. V.50. N8. P.1410-1418. DOI: 10.1023/A:1012785007135 WOS Scopus РИНЦ OpenAlex
Direct C-nitration of cyclic alpha,beta-unsaturated oximes under the action of sodium nitrite and acetic acid in methanol
Russian Chemical Bulletin. 2001. V.50. N8. P.1410-1418. DOI: 10.1023/A:1012785007135 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000173525900009 |
| Scopus: | 2-s2.0-0035528012 |
| РИНЦ: | 13363793 |
| OpenAlex: | W2951922788 |