Hydrocarbon conversion on ZSM-5 in the presence of N2O: relative reactivity and routes of product formation studied by GC-MS and C-13 NMR Full article
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Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Output data | Year: 2000, Volume: 158, Number: 1, Pages: 377-380 Pages count : DOI: 10.1016/S1381-1169(00)00108-4 | ||||
| Tags | ZSM-5; alkanes; N2O; relative reactivity; NMR | ||||
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Abstract:
Oxidative conversion of methane, ethane, propane, benzene, hydrogen and their binary mixtures R1-R2-N2O-He (where R1, R2 are substances under study) were studied on HZSM-5 at 350-450 degrees C. Relative reactivities were estimated, rate of conversion of hydrocarbons correlating with the strength of C-H bond. C-13 label distribution in the product of (CH4)-C-13-C6H6-N2O feed was studied by GC-MS, H-1 and C-13 NMR. It was shown that methane was capable to alkylate the aromatic ring under reaction condition, giving toluene and xylenes from benzene. (C) 2000 Elsevier Science B.V. All rights reserved.
Cite:
Vereshchagin S.
, Kirik N.
, Shishkina N.
, Morozov S.
, Shakirov M.
, Mamatyuk V.
, Anshits A.
Hydrocarbon conversion on ZSM-5 in the presence of N2O: relative reactivity and routes of product formation studied by GC-MS and C-13 NMR
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.377-380. DOI: 10.1016/S1381-1169(00)00108-4 WOS Scopus РИНЦ OpenAlex
Hydrocarbon conversion on ZSM-5 in the presence of N2O: relative reactivity and routes of product formation studied by GC-MS and C-13 NMR
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.377-380. DOI: 10.1016/S1381-1169(00)00108-4 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Sep 1, 2000 |
Identifiers:
| Web of science: | WOS:000089201200051 |
| Scopus: | 2-s2.0-0034622697 |
| Elibrary: | 13347808 |
| OpenAlex: | W1987904439 |