Reaction of guaianolide achillin with chlorine in methanol

Reaction of guaianolide achillin with chlorine in methanol Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2000, Volume: 49, Number: 9, Pages: 1624-1628 Pages count : DOI: 10.1007/BF02495170

Tags

sesquiterpenoids; guaianolides; achillin; chlorination; two-dimensional NMR spectroscopy; X-ray diffraction analysis

Authors

Alebastrov OV , Raldugin VA , Shakirov MM , Bagryanskaya IY , Gatilov YV , Kulyjasov AT , Adekenov SM , Tolstikov GA

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Minist Sci & Higher Educ Kazakhstan Republ, Inst Phytochem, Karaganda 470032, Kazakhstan

The reaction of sesquiterpene lactone achillin with chlorine in methanol afforded four products, viz., two monochlorides and two dichlorides. One of these monochlorides is an intermediate in the formation of both dichlorides. The structures of the reaction products were established by two-dimensional NMR spectroscopy. The structure of one of the products was also established by X-ray diffraction analysis.

Alebastrov O. , Raldugin V. , Shakirov M. , Bagryanskaya I. , Gatilov Y. , Kulyjasov A. , Adekenov S. , Tolstikov G.
Reaction of guaianolide achillin with chlorine in methanol
Russian Chemical Bulletin. 2000. V.49. N9. P.1624-1628. DOI: 10.1007/BF02495170 WOS Scopus РИНЦ OpenAlex

Published print:

Sep 1, 2000

≡ Web of science:	WOS:000171958400024
≡ Scopus:	2-s2.0-0034258426
≡ Elibrary:	13345432
≡ OpenAlex:	W2950618679