Sciact
  • EN
  • RU

Reactions of aromatic compounds with nucleophilic reagents in liquid ammonia: XVII. Effect of ionic association on the orientation in aryloxydefluorination of 2,4-difluoronitrobenzene Full article

Journal Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393
Output data Year: 2000, Volume: 36, Number: 6, Pages: 801-807 Pages count : 7 DOI: 10.1007/BF02757434
Authors Politanskaya L.V. 1 , Ryabitskaya E.V. 1 , Malykhin E.V. 1 , Steingartz V.D. 1
Affiliations
1 (Данные Web of science) Russian Acad Sci, Novosibirsk Organ Chem Inst, Siberian Div, Novosibirsk 630090, Russia

Abstract: The analysis of dependence of fluorine replacement orientation in 2,4-difluoronitrobenzene effected by nucleophiles Y-C6H4OM (Y = p-OMe, p-Me, m-Me, H, p-F, p-Cl, m-F, m-Cl; M = Li, Na, K, Et4N, Bu4N) in liquid ammonia medium at -35 degreesC on the nature of M, Y, on nucleophile concentration, on addition of crown ethers, diaminoalkanes, and dimethoxyethane indicates the occurrence of ionic association at M = K, Na.
Cite: Politanskaya L.V. , Ryabitskaya E.V. , Malykhin E.V. , Steingartz V.D.
Reactions of aromatic compounds with nucleophilic reagents in liquid ammonia: XVII. Effect of ionic association on the orientation in aryloxydefluorination of 2,4-difluoronitrobenzene
Russian Journal of Organic Chemistry. 2000. V.36. N6. P.801-807. DOI: 10.1007/BF02757434 WOS Scopus РИНЦ OpenAlex
Dates:
Published print: Jun 1, 2000
Identifiers:
Web of science: WOS:000166138500008
Scopus: 2-s2.0-0034195132
Elibrary: 13338463
OpenAlex: W2021997928
Citing:
DB Citing
Web of science 1
Scopus 1
Elibrary 1
Altmetrics: