Synthesis of nitrogen-containing heterocyclic compounds using perfluoro-2-methylpent-2-ene and perfluoro-5-azanon-4-ene

Synthesis of nitrogen-containing heterocyclic compounds using perfluoro-2-methylpent-2-ene and perfluoro-5-azanon-4-ene Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2000, Volume: 103, Number: 2, Pages: 105-115 Pages count : DOI: 10.1016/S0022-1139(99)00310-3

Tags

perfluoro-2-methylpent-2-ene; perfluoro-5-azanon-4-ene; pyrimidine; 2H-pyrido[1,2-a]pyrimidine; [1,3,5]triazine derivatives

Authors

Chi KW , Furin GG , Gatilov YV , Bagryanskay IY , Zhuzhgov EL

Affiliations

1	(Данные Web of science) Russian Acad Sci, Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia
2	(Данные Web of science) Univ Ulsan, Dept Chem, Ulsan 680749, South Korea
3	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

Reactions of perfluoro-2-methylpent-2-ena or perfluoro-5-azanon-4-ene with a range of bidentate nitrogen nucleophiles (urea, acet-, benz-, 4-nitrobenz-amidine hydrochloride, 2-aminopyridine, 2-aminobenzimidazole, guanidine) in the presence of Et3N or KOH effectively provided partially fluorinated heterocycles of pyrimidine, 2H-pyrido[1,2-a]pyrimidine and [1,3,5]triazine derivatives. The structure of 2-pentafluoroethyl-3-trifluoromethyl-pyrido[1,2-a]pyrimidin-4-one was further confirmed by the X-ray crystallographic analysis. (C) 2000 Elsevier Science S.A. All rights reserved.

Chi K. , Furin G. , Gatilov Y. , Bagryanskay I. , Zhuzhgov E.
Synthesis of nitrogen-containing heterocyclic compounds using perfluoro-2-methylpent-2-ene and perfluoro-5-azanon-4-ene
Journal of Fluorine Chemistry. 2000. V.103. N2. P.105-115. DOI: 10.1016/S0022-1139(99)00310-3 WOS Scopus РИНЦ OpenAlex

Published print:

Apr 1, 2000

Web of science:	WOS:000086871000003
Scopus:	2-s2.0-0003032354
Elibrary:	13336205
OpenAlex:	W2952547172

DB	Citing
Web of science	17
Scopus	24
Elibrary	24
OpenAlex	21