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Skeletal Transformations of the Arylation Products of Perfluoro(1,2-diethylbenzocyclobutene) with Tetrafluorobenzenes in the Presence of SbF5 Full article

Journal Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393
Output data Year: 2020, Volume: 56, Number: 3, Pages: 429-435 Pages count : 7 DOI: 10.1134/S1070428020030100
Tags perfluoro(1; 2-diethylcyclobutabenzene); tetrafluorobenzene; cation; skeletal transformations; antimony pentafluoride
Authors Mezhenkova T.V. 1 , Sinyakov V.R. 1 , Karpov V.M. 1 , Zonov Ya.V. 1,2
Affiliations
1 Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2 Novosibirsk National Research State University, Novosibirsk, 630090 Russia

Abstract: The reaction of perfluoro(1,2-diethylbenzocyclobutene) with 1,2,4,5-tetrafluorobenzene in SbF5, followed by hydrolysis, gave products resulting from expansion of the tetrafluorophenyl ring to cycloheptatriene. The title compound reacted with 1,2,3,5-tetrafluorobenzene to form products of opening of the four-membered ring. A similar reaction with 1,2,3,4-tetrafluorobenzene involved opening of the cyclobutane ring together with the formation of perfluoro(9,10-diethyl-9.10-dihydroanthracene) derivatives.
Cite: Mezhenkova T.V. , Sinyakov V.R. , Karpov V.M. , Zonov Y.V.
Skeletal Transformations of the Arylation Products of Perfluoro(1,2-diethylbenzocyclobutene) with Tetrafluorobenzenes in the Presence of SbF5
Russian Journal of Organic Chemistry. 2020. V.56. N3. P.429-435. DOI: 10.1134/S1070428020030100 WOS Scopus РИНЦ OpenAlex
Original: Меженкова Т.В. , Синяков В.Р. , Карпов В.М. , Зонов Я.В.
Скелетные превращения продуктов арилирования перфтор-1,2-диэтилбензоциклобутена тетрафторбензолами в присутствии sbf5
Журнал органической химии (RUSS J ORG CHEM+). 2020. Т.56. №3. С.422-429. DOI: 10.31857/S0514749220030118 РИНЦ OpenAlex
Dates:
Submitted: Nov 21, 2019
Accepted: Jan 17, 2020
Published print: Mar 1, 2020
Published online: Apr 22, 2020
Identifiers:
Web of science: WOS:000527931800010
Scopus: 2-s2.0-85083672795
Elibrary: 43271384
OpenAlex: W3019318453
Citing:
DB Citing
Web of science 1
Scopus 1
Elibrary 2
OpenAlex 1
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