Reaction or perfluoro-2-methylpent-2-ene with ethylenediamine and hexamethylenediamine

Reaction or perfluoro-2-methylpent-2-ene with ethylenediamine and hexamethylenediamine Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1999, Volume: 48, Number: 8, Pages: 1558-1562 Pages count : 5 DOI: 10.1007/BF02496412

Tags

nucleophilic substitution and addition; cyclization; perfluoro-2-methylpent-2-ene; ethylenediamine; hexamethylenediamine

Authors

Furin G.G. ¹ , Gatilov Yu .V. ¹ , Bagryanskaya I.Yu. ¹ , Zhuzhgov E.L. ²

Affiliations

1	Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation
2	Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian

Reaction of perfluoro-2-methylpent-2-ene: with ethylenediamine and hexamethylenediamine results in 9-fluoro-5,9-bis(pentafluoroethyl)-6,8,8-tris(trifluoromethyl)-1,4-diazabicyclo[5.2.0]nona-4,6-diene, whose structure was confirmed by X-ray analysis, and 11-pentafluoroethyl-10-trifluoromethl-1,8-diazabicyclo[7.2.0]undeca-8,10-diene, respectively. The reaction pathways are discussed.

Furin G.G. , Gatilov Y.V. , Bagryanskaya I.Y. , Zhuzhgov E.L.
Reaction or perfluoro-2-methylpent-2-ene with ethylenediamine and hexamethylenediamine
Russian Chemical Bulletin. 1999. V.48. N8. P.1558-1562. DOI: 10.1007/BF02496412 WOS Scopus РИНЦ OpenAlex

Published print:

Aug 1, 1999

≡ Web of science:	WOS:000083426200027
≡ Scopus:	2-s2.0-0033238502
≡ Elibrary:	13308607
≡ OpenAlex:	W2949738709