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Formation and study of thin films of tert-butyl-substituted thiopyrylium dyes Научная публикация

Журнал Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171
Вых. Данные Год: 1998, Том: 47, Номер: 7, Страницы: 1306-1312 Страниц : 7 DOI: 10.1007/BF02495553
Ключевые слова thiopyrylium dyes; tert-butyl substituents; thin films; electronic absorption spectra; structure of layers; intermolecular interactions
Авторы Shelkovnikov V.V. 1 , Gerasimova T.N. 1 , Ivanova Z.M. 1 , Orlova N.A. 1
Организации
1 Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Lavrent'eva, 630090, Novosibirsk, Russian Federation

Реферат: The formation of thin films of symmetrical and asymmetrical thiopyrylium dyes, containing tert-butyl substituents, on glass supports was studied. The films were deposited by centrifugation of solutions of individual dyes or dye-polymer [poly(methyl methacrylate)] compositions. The dye : polymer ratios necessary for the formation of WORM recording layers based on these dyes were determined. The use of a polymeric matrix increases the film thickness and optical density but decreases its reflection power and does not allow crystallization of the dye on the support to be completely avoided. An increase in the number of tert-butyl groups in the dye molecule prevents crystallization of the recording layer in the case of symmetrical dye molecules, but does not prevent it for asymmetrical molecules. The data obtained were interpreted in terms of geometrical views on the interaction of dye molecules in thin layers.
Библиографическая ссылка: Shelkovnikov V.V. , Gerasimova T.N. , Ivanova Z.M. , Orlova N.A.
Formation and study of thin films of tert-butyl-substituted thiopyrylium dyes
Russian Chemical Bulletin. 1998. V.47. N7. P.1306-1312. DOI: 10.1007/BF02495553 WOS Scopus РИНЦ OpenAlex
Даты:
Опубликована в печати: 1 июл. 1998 г.
Идентификаторы БД:
Web of science: WOS:000075335500012
Scopus: 2-s2.0-0032350568
РИНЦ: 13303123
OpenAlex: W1976852682
Цитирование в БД:
БД Цитирований
Web of science 1
Scopus 1
РИНЦ 2
OpenAlex 1
Альметрики: