Reactions of methyl(pentafluorophenyl)- and methyl(pentafluorophenyl)phenylsilanes with electrophiles. A convenient preparative route to halogeno(methyl)pentafluorophenylsilanes C6F5SiMe2X and C6F5SiMeX2 (X = F, Cl and Br) Научная публикация
| Журнал |
Journal of Organometallic Chemistry
ISSN: 0022-328X |
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| Вых. Данные | Год: 1998, Том: 570, Номер: 2, Страницы: 255-263 Страниц : 9 DOI: 10.1016/S0022-328X(98)00805-5 | ||||
| Ключевые слова | silanes; electrophilic substitution | ||||
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Реферат:
Halogeno(methyl)pentafluorophenylsilanes C6F5SiMenX3-n (n = 1, 2) (X = F, Cl, Br) were prepared in good yields from the corresponding phenylsilanes C6F5SiMenPh3-n by reactions with the electrophiles aHF, HCl-AlCl3, Br-2-AlBr3 or AlX3 (X = Cl, Br) halogenated hydrocarbons. Additionally, reactions of C6F5SiMe3 and (C6F5)(2)SiMe2 with selected electrophiles were studied. (C) 1998 Elsevier Science S.A. All rights reserved.
Библиографическая ссылка:
Frohn H.J.
, Lewin A.
, Bardin V.V.
Reactions of methyl(pentafluorophenyl)- and methyl(pentafluorophenyl)phenylsilanes with electrophiles. A convenient preparative route to halogeno(methyl)pentafluorophenylsilanes C6F5SiMe2X and C6F5SiMeX2 (X = F, Cl and Br)
Journal of Organometallic Chemistry. 1998. V.570. N2. P.255-263. DOI: 10.1016/S0022-328X(98)00805-5 WOS Scopus РИНЦ OpenAlex
Reactions of methyl(pentafluorophenyl)- and methyl(pentafluorophenyl)phenylsilanes with electrophiles. A convenient preparative route to halogeno(methyl)pentafluorophenylsilanes C6F5SiMe2X and C6F5SiMeX2 (X = F, Cl and Br)
Journal of Organometallic Chemistry. 1998. V.570. N2. P.255-263. DOI: 10.1016/S0022-328X(98)00805-5 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 нояб. 1998 г. |
Идентификаторы БД:
| Web of science: | WOS:000076724200012 |
| Scopus: | 2-s2.0-0011873437 |
| РИНЦ: | 13279795 |
| OpenAlex: | W2026513762 |