The formation of nitroxyl radicals in reactions of dimethyldioxirane with 2,2,6,6-tetramethylpiperidine and 2,2,5,5-tetramethyl-3-imidazoline-3-oxid derivatives

The formation of nitroxyl radicals in reactions of dimethyldioxirane with 2,2,6,6-tetramethylpiperidine and 2,2,5,5-tetramethyl-3-imidazoline-3-oxid derivatives Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1998, Volume: 47, Number: 12, Pages: 2419-2421 Pages count : 3 DOI: 10.1007/BF02641545

Tags

dimethyldioxirane; secondary amines; nitroxyl radicals; chemiluminescence

Authors

Kabal'nova N.N. ¹ , Grabovsky S.A. ¹ , Shishlov N.M. ¹ , Shereshovets V.V. ¹ , Volodarskii L.B. ² , Tolstikov G.A. ²

Affiliations

1	Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation
2	Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

The oxidation of secondary and tertiary amines, derivatives of 2,2,6,6-tetramethyipiperidine and 2,2,5,5-tetramethyl-3-imidazoline-3-oxide, by dimethyldioxirane results in the formation of nitroxyl radicals, which induce the decomposition of dimethyldioxirane. Chemiluminescence in the IR and visible regions during the reaction of dimethyldioxirane with 2,2,6,6-tetramethyl-4-hydroxypiperidine-1-oxyl was observed.

Kabal'nova N.N. , Grabovsky S.A. , Shishlov N.M. , Shereshovets V.V. , Volodarskii L.B. , Tolstikov G.A.
The formation of nitroxyl radicals in reactions of dimethyldioxirane with 2,2,6,6-tetramethylpiperidine and 2,2,5,5-tetramethyl-3-imidazoline-3-oxid derivatives
Russian Chemical Bulletin. 1998. V.47. N12. P.2419-2421. DOI: 10.1007/BF02641545 WOS Scopus РИНЦ OpenAlex

Published print:

Dec 1, 1998

Web of science:	WOS:000079263800016
Scopus:	2-s2.0-0032251453
Elibrary:	13304701
OpenAlex:	W2952845498

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