Bis(2,1,3-benzotelluradiazolidyl)2,1,3-benzotelluradiazole: a pair of radical anions coupled by Te-N chalcogen bonding

Bis(2,1,3-benzotelluradiazolidyl)2,1,3-benzotelluradiazole: a pair of radical anions coupled by Te-N chalcogen bonding Full article

Journal

Chemical Communications
ISSN: 1359-7345

Output data

Year: 2020, Volume: 56, Number: 7, Pages: 1113-1116 Pages count : 4 DOI: 10.1039/c9cc08110k

Authors

Puskarevsky Nikolay A. ^1,2 , Smolentsev Anton, I ^1,2 , Dmitriev Alexey A. ^3,4 , Vargas-Baca Ignacio ⁵ , Gritsan Nina P. ^3,4 , Beckmann Jens ⁶ , Zibarev Andrey, V ^4,7

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 63000, Russia
2	(Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 63000, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Branch, Voevodsky Inst Chem Kinet & Combust, Novosibirsk 630090, Russia
4	(Данные Web of science) Novosibirsk State Univ, Dept Phys, Novosibirsk 63000, Russia
5	(Данные Web of science) McMaster Univ, Dept Chem & Chem Biol, 1280 Main St W, Hamilton, ON L8S 4M1, Canada
6	(Данные Web of science) Univ Bremen, Inst Inorgan Chem & Crystallog, D-28359 Bremen, Germany
7	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

Reduction of 2,1,3-benzotelluradiazole (3) yielded a crystalline solid that features a trimeric dianion formally composed of two [3](-) and one 3 bridged by unusually asymmetric TeMIDLINE HORIZONTAL ELLIPSISN chalcogen bonds. The solid is diamagnetic due to strong antiferromagnetic coupling, as revealed by CASSCF/CASPT2 and BS-DFT.

Puskarevsky N.A. , Smolentsev A.I. , Dmitriev A.A. , Vargas-Baca I. , Gritsan N.P. , Beckmann J. , Zibarev A.V.
Bis(2,1,3-benzotelluradiazolidyl)2,1,3-benzotelluradiazole: a pair of radical anions coupled by Te-N chalcogen bonding
Chemical Communications. 2020. V.56. N7. P.1113-1116. DOI: 10.1039/c9cc08110k WOS Scopus РИНЦ OpenAlex

Web of science:	WOS:000508933700021
Scopus:	2-s2.0-85078403494
Elibrary:	43250623
OpenAlex:	W2996266437

DB	Citing
Web of science	17
Scopus	17
Elibrary	17
OpenAlex	21