Transformations of perfluoroxylenes and perfluoro-p-cymene under the action of Zn(Cu)-DMF-H2O. Full article
| Journal |
Tetrahedron
ISSN: 0040-4020 |
||
|---|---|---|---|
| Output data | Year: 1997, Volume: 53, Number: 5, Pages: 1797-1812 Pages count : 16 DOI: 10.1016/S0040-4020(96)01090-3 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
Perfluorinated xylenes and perfluoro-para-cymene undergo hydrodefluorination under the action of Zn(Cu)-DMF-H2O. Hydrogen enters mainly at the benzyl position of para-dialkylbenzenes and at the para position to perfluoroalkyl groups of perfluorinated ortho- and meta-xylenes. The process presumably involves radical anions as intermediates. A product of perfluoro-4-methylbenzyl radical trapping by hexene-1 was obtained Quantum-chemical calculations of radical anions of the compounds under investigation have been carried out. (C) 1997, Elsevier Science Ltd.
Cite:
Krasnov V.I.
, Platonov V.E.
, Beregovaya I.V.
, Shchegoleva L.N.
Transformations of perfluoroxylenes and perfluoro-p-cymene under the action of Zn(Cu)-DMF-H2O.
Tetrahedron. 1997. V.53. N5. P.1797-1812. DOI: 10.1016/S0040-4020(96)01090-3 WOS Scopus РИНЦ OpenAlex
Transformations of perfluoroxylenes and perfluoro-p-cymene under the action of Zn(Cu)-DMF-H2O.
Tetrahedron. 1997. V.53. N5. P.1797-1812. DOI: 10.1016/S0040-4020(96)01090-3 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Feb 1, 1997 |
Identifiers:
| Web of science: | WOS:A1997WF28300027 |
| Scopus: | 2-s2.0-0031550585 |
| Elibrary: | 13259657 |
| OpenAlex: | W1967221220 |