Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino)phosphine .6. Reactions of halogenotetrafluorobenzenes RC6F4X (X=Cl, Br, or I) with chlorotrimethylsilane Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 1997, Volume: 46, Number: 4, Pages: 780-785 Pages count : 6 DOI: 10.1007/BF02495213 | ||
| Tags | halogenotetrafluorobenzenes; dihalogenotetrafluorobenzenes; tris(diethylamino)phosphine; silyldehalogenation; silyldeprotonation | ||
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Abstract:
The rate of replacement of the halogen atom in isomers of RC6F4X (X = Cl, Br, or I) by the SiMe3 group under the action of Me3SiCl and P(NEt2)(3) depends on the nature and the mutual arrangement of the substituents X and R. In addition to silyldehalogenation, compounds C6HF4X (X = Br or I) undergo silyldeprotonation and reduction to tetrafluorobenzenes.
Cite:
Bardin V.V.
Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino)phosphine .6. Reactions of halogenotetrafluorobenzenes RC6F4X (X=Cl, Br, or I) with chlorotrimethylsilane
Russian Chemical Bulletin. 1997. V.46. N4. P.780-785. DOI: 10.1007/BF02495213 WOS Scopus РИНЦ OpenAlex
Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino)phosphine .6. Reactions of halogenotetrafluorobenzenes RC6F4X (X=Cl, Br, or I) with chlorotrimethylsilane
Russian Chemical Bulletin. 1997. V.46. N4. P.780-785. DOI: 10.1007/BF02495213 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Apr 1, 1997 |
Identifiers:
| Web of science: | WOS:A1997XN59600029 |
| Scopus: | 2-s2.0-0031527418 |
| Elibrary: | 13251295 |
| OpenAlex: | W2949343853 |