Method of preparation of alkylated 1,3-diphenylpropan-2-ones, the components for assembly of graphene nanostructures Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 2020, Volume: 69, Number: 1, Pages: 172-175 Pages count : 4 DOI: 10.1007/s11172-020-2740-8 | ||||
| Tags | Grignard reagents; cross-coupling reactions; alkylation; long-chain 1; 3-dialkyl-phenyl-2-propanones | ||||
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Abstract:
Long-chain alkylated 1,3-diphenyl-2-propanones are used in the synthesis of graphene nanostructures (graphene nanoribbons and quantum dots). A reliable procedure to obtain mono- or dialkylated diphenyl-2-propanones in 26 and 38% yields has been proposed. The method includes the dioxolane protection of the keto group in 1,3-di-(4-bromophenyl)-2-propanone, then a palladium-catalyzed cross-coupling reaction of the obtained dioxolane with one-and-a-half- or four-fold excess of dodecyl magnesium bromide that leads to a predominant formation of mono- or dialkylation products respectively, followed by hydrolysis of dioxolanes at the last stage to form the desired diphenyl-2-propanones.
Cite:
Ten Y.A.
, Troshkova N.M.
, Tretyakov E.V.
Method of preparation of alkylated 1,3-diphenylpropan-2-ones, the components for assembly of graphene nanostructures
Russian Chemical Bulletin. 2020. V.69. N1. P.172-175. DOI: 10.1007/s11172-020-2740-8 WOS Scopus РИНЦ OpenAlex
Method of preparation of alkylated 1,3-diphenylpropan-2-ones, the components for assembly of graphene nanostructures
Russian Chemical Bulletin. 2020. V.69. N1. P.172-175. DOI: 10.1007/s11172-020-2740-8 WOS Scopus РИНЦ OpenAlex
Original:
Тен Ю.А.
, Трошкова Н.М.
, Третьяков Е.В.
МЕТОД ПОЛУЧЕНИЯ АЛКИЛИРОВАННЫХ 1,3-ДИФЕНИЛПРОПАН-2-ОНОВ - КОМПОНЕНТОВ СБОРКИ ГРАФЕНОВЫХ НАНОСТРУКТУР
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 2020. №1. С.172-175. РИНЦ
МЕТОД ПОЛУЧЕНИЯ АЛКИЛИРОВАННЫХ 1,3-ДИФЕНИЛПРОПАН-2-ОНОВ - КОМПОНЕНТОВ СБОРКИ ГРАФЕНОВЫХ НАНОСТРУКТУР
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 2020. №1. С.172-175. РИНЦ
Dates:
| Published print: | Jan 1, 2020 |
| Published online: | Apr 8, 2020 |
Identifiers:
| Web of science: | WOS:000524864100023 |
| Scopus: | 2-s2.0-85083320664 |
| Elibrary: | 43293035 |
| OpenAlex: | W3015679466 |