Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino) phosphines .8. Replacement of fluorine by hydrogen in polyfluoroaromatic compounds Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 1997, Volume: 46, Number: 8, Pages: 1434-1436 Pages count : 3 DOI: 10.1007/BF02505680 | ||
| Tags | polyfluoroarenes; reduction; tris(diethylamino)phosphine | ||
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Abstract:
When reacted with P(NEt2)(3) and a proton donor, pentafluoropyridine, 3-chlorotetrafluoropyridine, pentafluorobenzonitrile, and octafluorotoluene yield products of replacement of the fluorine atom by hydrogen at position 4. This process is accompanied by the side reaction of aminodefluorination. In the case of 3-H-heptafluorotoluene and octafluoronaphthalene, aminodefluorination is the main reaction. Reactions of perfluoro-4-isopropyltoluene, 4-H-heptafluorotoluene, and 4-methylheptafluorotoluene do not occur under the above-mentioned conditions.
Cite:
Bardin V.V.
Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino) phosphines .8. Replacement of fluorine by hydrogen in polyfluoroaromatic compounds
Russian Chemical Bulletin. 1997. V.46. N8. P.1434-1436. DOI: 10.1007/BF02505680 WOS Scopus РИНЦ OpenAlex
Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino) phosphines .8. Replacement of fluorine by hydrogen in polyfluoroaromatic compounds
Russian Chemical Bulletin. 1997. V.46. N8. P.1434-1436. DOI: 10.1007/BF02505680 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Aug 1, 1997 |
Identifiers:
| Web of science: | WOS:A1997YE52900013 |
| Scopus: | 2-s2.0-0031495908 |
| Elibrary: | 13269433 |
| OpenAlex: | W2335349394 |