Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates Full article
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Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350 |
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| Output data | Year: 2020, Volume: 90, Number: 1, Pages: 50-61 Pages count : DOI: 10.1134/S1070363220010089 | ||||
| Tags | aryldihaloboranes; aryltrifluoroborates; boron halides; aluminum halides | ||||
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Abstract:
Fluorine-containing aryldihalogenoboranes have been obtained by the reaction of boron and aluminum chlorides and bromides with potassium aryltrifluoroborates K[ArBF3] under mild conditions. In a similar way, bis(pentafluorophenyl)halogenoboranes have been synthesized by the reaction with K[(C6F5)(2)BF2]. The reaction of K[C6F5BF3] with AlBr3 affords a mixture of C6F5BF2 and C6F5BCl2 due to fast conversion of AlBr3 to AlBrCl2. The inductive and resonance parameters of BCl2 and BBr2 groups were calculated.
Cite:
Bardin V.V.
, Prikhod'ko S.A.
, Shmakov M.M.
, Shabalin A.Y.
, Adonin N.Y.
Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates
Russian Journal of General Chemistry. 2020. V.90. N1. P.50-61. DOI: 10.1134/S1070363220010089 WOS Scopus РИНЦ OpenAlex
Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates
Russian Journal of General Chemistry. 2020. V.90. N1. P.50-61. DOI: 10.1134/S1070363220010089 WOS Scopus РИНЦ OpenAlex
Original:
Бардин В.В.
, Приходько С.А.
, Шмаков М.М.
, Шабалин А.Ю.
, Адонин Н.Ю.
СИНТЕЗ ФТОРСОДЕРЖАЩИХ АРИЛ(ГАЛОГЕН)БОРАНОВ ИЗ АРИЛ(ФТОР)БОРАТОВ КАЛИЯ
Журнал общей химии (RUSS J GEN CHEM+). 2010. Т.90. №1. С.72-84. DOI: 10.31857/S0044460X20010096 РИНЦ OpenAlex
СИНТЕЗ ФТОРСОДЕРЖАЩИХ АРИЛ(ГАЛОГЕН)БОРАНОВ ИЗ АРИЛ(ФТОР)БОРАТОВ КАЛИЯ
Журнал общей химии (RUSS J GEN CHEM+). 2010. Т.90. №1. С.72-84. DOI: 10.31857/S0044460X20010096 РИНЦ OpenAlex
Dates:
| Published print: | Jan 1, 2020 |
| Published online: | Mar 26, 2020 |
Identifiers:
| Web of science: | WOS:000521739700008 |
| Scopus: | 2-s2.0-85082666616 |
| Elibrary: | 43263503 |
| OpenAlex: | W3013115111 |