Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride .2. Electrophilic oxygenation of pentafluorobenzene derivatives C(6)F(5)X Full article
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Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
ISSN: 0932-0776 |
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| Output data | Year: 1996, Volume: 51, Number: 7, Pages: 1015-1021 Pages count : 7 DOI: 10.1515/znb-1996-0718 | ||||
| Tags | xenon difluoride; electrophilic oxygenation; polyfluorobenzenes; polyfluorinated 1,4-cyclohexadienones; epoxidation | ||||
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Abstract:
Electrophilic oxygenation of polyfluorobenzenes C6F5 X (X = F, Cl, Br, H, CF3, NH3+, NMe(3)(+), OH and OCH2CF3) with XeF2 and H2O in HF leads to the formation of polyfluorinated 1,4-cyclohexadienones. Pentafluoroiodobenzene is converted into C6F5IF2 and C6F5IF4, whereas [C6F5N2](+) [NbF6](-) is unreactive towards this new type of electrophilic oxygenation.
Cite:
Frohn H.J.
, Bardin V.V.
Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride .2. Electrophilic oxygenation of pentafluorobenzene derivatives C(6)F(5)X
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 1996. V.51. N7. P.1015-1021. DOI: 10.1515/znb-1996-0718 WOS Scopus OpenAlex
Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride .2. Electrophilic oxygenation of pentafluorobenzene derivatives C(6)F(5)X
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 1996. V.51. N7. P.1015-1021. DOI: 10.1515/znb-1996-0718 WOS Scopus OpenAlex
Dates:
| Published print: | Jul 1, 1996 |
| Published online: | Jun 2, 2014 |
Identifiers:
| Web of science: | WOS:A1996VB44700018 |
| Scopus: | 2-s2.0-0040749720 |
| OpenAlex: | W2081992410 |