Derivatives of dihydropyrazine-1,4-dioxide, 3-imidazoline 3-oxide, and alpha-phenyl nitrones with functional groups as new spin traps in solution and in the gas phase Научная публикация
| Журнал |
Journal of Physical Chemistry
ISSN: 0022-3654 |
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| Вых. Данные | Год: 1996, Том: 100, Номер: 44, Страницы: 17523-17527 Страниц : 5 DOI: 10.1021/jp960438e | ||||
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Реферат:
The title compounds, acyclic phenyl nitrones with functional groups, cyclic dinitrones with conjugated or isolated double bonds, and imidazoline nitrones are studied as spin traps (ST) for short-lived free radicals (R) generated photochemically in solution and in the gas phase. New STs are efficient in trapping OH, hydroxyalkyl, or HO2 radicals. EPR spectra of the spin adducts (SA) of studied dinitrones are triplets of doublets characteristic of the nitroxides with one radical center. Imidazoline ST with amino nitrogen exhibits pH-dependent hyperfine splittings of its SAs. Some spin traps were shown to be efficient in detecting R in the atmospheric experiments.
Библиографическая ссылка:
Dultseva G.G.
, Skubnevskaya G.I.
, Tikhonov A.Y.
, Mazhukin D.G.
, Volodarsky L.V.
Derivatives of dihydropyrazine-1,4-dioxide, 3-imidazoline 3-oxide, and alpha-phenyl nitrones with functional groups as new spin traps in solution and in the gas phase
Journal of Physical Chemistry. 1996. V.100. N44. P.17523-17527. DOI: 10.1021/jp960438e WOS Scopus РИНЦ OpenAlex
Derivatives of dihydropyrazine-1,4-dioxide, 3-imidazoline 3-oxide, and alpha-phenyl nitrones with functional groups as new spin traps in solution and in the gas phase
Journal of Physical Chemistry. 1996. V.100. N44. P.17523-17527. DOI: 10.1021/jp960438e WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 янв. 1996 г. |
Идентификаторы БД:
| Web of science: | WOS:A1996VR07600014 |
| Scopus: | 2-s2.0-0005171599 |
| РИНЦ: | 13239794 |
| OpenAlex: | W2953191007 |