POLYMER-FILMS OF J-AGGREGATED CYANINE DYES AND METAL-CLUSTERS FOR NONLINEAR-OPTICAL APPLICATIONS

POLYMER-FILMS OF J-AGGREGATED CYANINE DYES AND METAL-CLUSTERS FOR NONLINEAR-OPTICAL APPLICATIONS Full article

Journal

Journal of Materials Chemistry
ISSN: 0959-9428

Output data

Year: 1995, Volume: 5, Number: 9, Pages: 1331-1334 Pages count : 4 DOI: 10.1039/jm9950501331

Authors

Shelkovnikov V.V. ¹ , Zhuravlev F.A. ¹ , Orlova N.A. ¹ , Plekhanov A.I. ² , Safonov V.P. ²

Affiliations

1	Novosibirsk Institute of Organic Chemistry, Novosibirsk, 630090
2	Institute of Automation and Electrometry, Novosibirsk 630090

A new medium with non-linear optical properties, comprising J-aggregates of cyanine dyes entrapped in a polymer matrix is reported. Pseudoisocyanine and benzothiazolium dyes with C2H5 and C18H37 chains were synthesized; Langmuir-Blodgett and polymer films of these dyes were prepared. The temperature stability of the J-aggregates in films was investigated by optical spectroscopy. J-Aggregates in polymer films display a higher thermal stability than those in Langmuir-Blodgett films and can be used in non-linear susceptibility experiments. The cubic susceptibility of the films was measured by four-wave mixing and found to be 0.8 x 10(-7) cm(3) erg(-1) for the degenerate case, Upon addition of metal clusters to the J-aggregate-polymer composite, an increase by a factor of > 30 in the susceptibility was observed.

Shelkovnikov V.V. , Zhuravlev F.A. , Orlova N.A. , Plekhanov A.I. , Safonov V.P.
POLYMER-FILMS OF J-AGGREGATED CYANINE DYES AND METAL-CLUSTERS FOR NONLINEAR-OPTICAL APPLICATIONS
Journal of Materials Chemistry. 1995. V.5. N9. P.1331-1334. DOI: 10.1039/jm9950501331 WOS Scopus РИНЦ OpenAlex

Web of science:	WOS:A1995RU09400008
Scopus:	2-s2.0-0000876734
Elibrary:	30855632
OpenAlex:	W1975900947

DB	Citing
Web of science	27
Scopus	28
Elibrary	27
OpenAlex	21