SELECTIVE ORTHO-ARYLATION OF POLYFLUORINATED HYDROXYAROMATIC COMPOUNDS WITH LEAD ARYL ACETATES Full article
| Journal |
Journal of Fluorine Chemistry
ISSN: 0022-1139 |
||
|---|---|---|---|
| Output data | Year: 1993, Volume: 63, Number: 3, Pages: 243-251 Pages count : 9 DOI: 10.1016/S0022-1139(00)80568-0 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
Reactions of salts of pentafluorophenol and heptafluoronaphthols with lead aryl acetates have led to the formation of arylcyclohexadienones with an ortho-quinoid structure. The arylation of sodium pentafluorophenoxide and heptafluoro-2-naphthoxide is accompanied by nucleophilic substitution of fluorine at a double bond by pentafluorophenoxy and heptafluoro-2-naphthoxy groups, respectively. Reduction of the resulting arylcyclohexadienones gave polyfluorinated phenols and naphthols with aryl and hydroxy groups in the 1,2-position.
Cite:
Kovtonyuk V.N.
, Kobrina L.S.
SELECTIVE ORTHO-ARYLATION OF POLYFLUORINATED HYDROXYAROMATIC COMPOUNDS WITH LEAD ARYL ACETATES
Journal of Fluorine Chemistry. 1993. V.63. N3. P.243-251. DOI: 10.1016/S0022-1139(00)80568-0 WOS Scopus OpenAlex
SELECTIVE ORTHO-ARYLATION OF POLYFLUORINATED HYDROXYAROMATIC COMPOUNDS WITH LEAD ARYL ACETATES
Journal of Fluorine Chemistry. 1993. V.63. N3. P.243-251. DOI: 10.1016/S0022-1139(00)80568-0 WOS Scopus OpenAlex
Dates:
| Published print: | Aug 1, 1993 |
Identifiers:
| Web of science: | WOS:A1993LP18800007 |
| Scopus: | 2-s2.0-0010775564 |
| OpenAlex: | W2005980715 |