FLUORO-INDENES .14. INTERACTION OF PERFLUORINATED 3-METHYLINDENE AND 1-METHYLENE-INDAN WITH NITRATING AGENTS IN ANHYDROUS HF Full article
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Output data | Year: 1993, Volume: 65, Number: 1-2, Pages: 29-35 Pages count : 7 DOI: 10.1016/S0022-1139(00)80469-8 | ||
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Abstract:
The reaction of perfluorinated 3-methyl-indene and 1-methylene-indan with nitrating agents in anhydrous HF leads to the formation of perfluoro-indan containing an oxygen function together with nitrofluorination products. From an analysis of the experimental data and the results of MNDO calculations of the starting compounds (including perfluorinated indene and 2-methyl-indene), their radical cations and polyfluorinated nitro-indanyl cations, a scheme for the process has been suggested including both a classical electrophilic route and a route involving radical cations of the substrates. The latter are assumed to be generated together with NO2. from the intermediate nitro-indanyl cations.
Cite:
Chuikov I.P.
, Karpov V.M.
, Platonov V.E.
, Beregovaya I.V.
, Shchegoleva L.N.
FLUORO-INDENES .14. INTERACTION OF PERFLUORINATED 3-METHYLINDENE AND 1-METHYLENE-INDAN WITH NITRATING AGENTS IN ANHYDROUS HF
Journal of Fluorine Chemistry. 1993. V.65. N1-2. P.29-35. DOI: 10.1016/S0022-1139(00)80469-8 WOS Scopus OpenAlex
FLUORO-INDENES .14. INTERACTION OF PERFLUORINATED 3-METHYLINDENE AND 1-METHYLENE-INDAN WITH NITRATING AGENTS IN ANHYDROUS HF
Journal of Fluorine Chemistry. 1993. V.65. N1-2. P.29-35. DOI: 10.1016/S0022-1139(00)80469-8 WOS Scopus OpenAlex
Dates:
| Published print: | Nov 1, 1993 |
Identifiers:
| Web of science: | WOS:A1993MK67700007 |
| Scopus: | 2-s2.0-0008560148 |
| OpenAlex: | W2028626859 |