VICINAL C-13-C-13 COUPLING-CONSTANTS IN BICYCLIC MONOTERPENES Full article
| Journal |
Magnetic Resonance in Chemistry
ISSN: 0749-1581 , E-ISSN: 1097-458X |
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| Output data | Year: 1992, Volume: 30, Number: 2, Pages: 95-100 Pages count : 6 DOI: 10.1002/mrc.1260300202 | ||
| Tags | C-13 NMR; C-13-C-13 COUPLING CONSTANTS; SELECTIVE VERSION OF INADEQUATE; 3-CARENE; ALPHA-PINENE; CAMPHENE | ||
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Abstract:
Carbon-carbon coupling constants in monoterpene hydrocarbons (3-carene, alpha-pinene and camphene) were investigated. A selective version of the INADEQUATE experiment was used for measurements of the long-range (n)J(CC) values. The dependence of the vicinal C-13-C-13 coupling constants on the dihedral angles and the types of molecular framework involved within the direct coupling path is discussed. The configuration of a heteroatomic derivative from alpha-pinene was determined from its 3J(CC) values.
Cite:
Denisov A.Y.
, Tkachev A.V.
, Mamatyuk V.I.
VICINAL C-13-C-13 COUPLING-CONSTANTS IN BICYCLIC MONOTERPENES
Magnetic Resonance in Chemistry. 1992. V.30. N2. P.95-100. DOI: 10.1002/mrc.1260300202 WOS Scopus РИНЦ OpenAlex
VICINAL C-13-C-13 COUPLING-CONSTANTS IN BICYCLIC MONOTERPENES
Magnetic Resonance in Chemistry. 1992. V.30. N2. P.95-100. DOI: 10.1002/mrc.1260300202 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Feb 1, 1992 |
Identifiers:
| Web of science: | WOS:A1992HD22100001 |
| Scopus: | 2-s2.0-84989085790 |
| Elibrary: | 31037917 |
| OpenAlex: | W1972140722 |