REACTIONS OF TRIMETHYLSILYLPENTAFLUOROBENZENE AND TRIETHYLGERMYLPENTAFLUOROBENZENE WITH NUCLEOPHILIC-REAGENTS Full article
| Journal |
Journal of Fluorine Chemistry
ISSN: 0022-1139 |
||
|---|---|---|---|
| Output data | Year: 1992, Volume: 59, Number: 2, Pages: 165-177 Pages count : 13 DOI: 10.1016/S0022-1139(00)82406-9 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
This paper reports the results of studies on the reactions of trialkylsilyl- and germylpentafluorobenzenes with O-, N, S- and C-nucleophiles, and with LiAlH4. DePending on the nature of the nucleophilic reagent, its attack is oriented towards a heteroatom (RO-, RS-), the C-4 atom of the pentafluorophenyl ring (BuLi, LiAlH4, piperidyl-lithium) or at both electrophilic centres (piperidine, RS-).
Cite:
Bardin V.V.
, Rogoza L.N.
, Stennikova I.V.
, Furin G.G.
REACTIONS OF TRIMETHYLSILYLPENTAFLUOROBENZENE AND TRIETHYLGERMYLPENTAFLUOROBENZENE WITH NUCLEOPHILIC-REAGENTS
Journal of Fluorine Chemistry. 1992. V.59. N2. P.165-177. DOI: 10.1016/S0022-1139(00)82406-9 WOS Scopus OpenAlex
REACTIONS OF TRIMETHYLSILYLPENTAFLUOROBENZENE AND TRIETHYLGERMYLPENTAFLUOROBENZENE WITH NUCLEOPHILIC-REAGENTS
Journal of Fluorine Chemistry. 1992. V.59. N2. P.165-177. DOI: 10.1016/S0022-1139(00)82406-9 WOS Scopus OpenAlex
Dates:
| Published print: | Nov 1, 1992 |
Identifiers:
| Web of science: | WOS:A1992KA45900001 |
| Scopus: | 2-s2.0-0000946405 |
| OpenAlex: | W2077752648 |