FLUOROINDENES .13. TRANSFORMATIONS OF POLYFLUORINATED INDENES AND 1-ALKYLIDENEINDANS IN THE H2O2-HF-SBF5 SYSTEM Full article
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BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE
ISSN: 1063-5211 |
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| Output data | Year: 1992, Volume: 41, Number: 6, Pages: 1104-1110 Pages count : 7 DOI: 10.1007/BF00866597 | ||
| Tags | POLYFLUORINATED INDENES; ALKYLIDENEINDANS; ELECTROPHILIC HYDROXYFLUORINATION; POLYFLUORINATED KETONES; BAEYER-VILLIGER REACTION | ||
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Abstract:
The reaction of perfluorinated indene, 3-methylindene, and 1-methylene- and 1-ethylideneindans with hydrogen peroxide in the hydrogen fluoride-antimony pentafluoride medium takes place at the multiple bond of the substrate and leads to the oxo derivatives of indan. The process probably takes place through the electrophilic addition of HO+. The C=C bond in perfluoro-3-methylindenone is not affected. In this compound and also in perfluoro-2-indanone and perfluoro-1-methyl-2-indanone the carbonyl group is involved in reaction with hydrogen peroxide in the HF-SbF5 system, and six-membered oxygen-containing heterocyclic compounds are formed.
Cite:
Chuikov I.P.
, Karpov V.M.
, Platonov V.E.
FLUOROINDENES .13. TRANSFORMATIONS OF POLYFLUORINATED INDENES AND 1-ALKYLIDENEINDANS IN THE H2O2-HF-SBF5 SYSTEM
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE. 1992. V.41. N6. P.1104-1110. DOI: 10.1007/BF00866597 WOS Scopus РИНЦ OpenAlex
FLUOROINDENES .13. TRANSFORMATIONS OF POLYFLUORINATED INDENES AND 1-ALKYLIDENEINDANS IN THE H2O2-HF-SBF5 SYSTEM
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE. 1992. V.41. N6. P.1104-1110. DOI: 10.1007/BF00866597 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Jun 1, 1992 |
Identifiers:
| Web of science: | WOS:A1992KU70200012 |
| Scopus: | 2-s2.0-33750933071 |
| Elibrary: | 31430642 |
| OpenAlex: | W2024264900 |