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ELECTROCHEMICAL OXIDATION OF 3-IMIDAZOLINE 3-OXIDES Full article

Journal BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE
ISSN: 1063-5211
Output data Year: 1992, Volume: 41, Number: 11, Pages: 2003-2007 Pages count : 5 DOI: 10.1007/BF00863363
Tags OXIDATION; 3-IMIDAZOLINE 3-OXIDES
Authors Kursakina I.G. 1 , Starichenko V.F. 1 , Grigorev I.A. 1
Affiliations
1 Institute of Organic Chemistry, Russian Academy of Sciences, 630090 Novosibirsk

Abstract: Cyclic voltammetry was used to study the electrochemical oxidation of substituted 3-imidazoline 3-oxides, It was determined that the oxidation potentials (E(p/2)) of the compounds depend on the nature of the substituents in the 1 and 4 positions of the ring. A correlation analysis of E(p/2) of the compounds and sigma(I) and sigma(R) of the substituent constants in the 4 position of the ring was carried out. The obtained results show that oxidation of 3-imidazoline 3-oxides can occur at the nitrone or amine fragment, depending on the nature of the substituent in the 1 position of the ring.
Cite: Kursakina I.G. , Starichenko V.F. , Grigorev I.A.
ELECTROCHEMICAL OXIDATION OF 3-IMIDAZOLINE 3-OXIDES
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE. 1992. V.41. N11. P.2003-2007. DOI: 10.1007/BF00863363 WOS Scopus OpenAlex
Dates:
Published print: Nov 1, 1992
Identifiers:
Web of science: WOS:A1992LK12600014
Scopus: 2-s2.0-34249842818
OpenAlex: W2009343680
Citing:
DB Citing
Web of science 1
Scopus 2
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