SYNTHESIS OF BICYCLIC BETA-OXO NITRONES - DERIVATIVES OF 6-AZABICYCLO[3.2.1]OCTANE AND THEIR REACTIONS WITH NUCLEOPHILIC-REAGENTS

SYNTHESIS OF BICYCLIC BETA-OXO NITRONES - DERIVATIVES OF 6-AZABICYCLO[3.2.1]OCTANE AND THEIR REACTIONS WITH NUCLEOPHILIC-REAGENTS Full article

Journal

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230

Output data

Year: 1991, Volume: 40, Number: 3, Pages: 597-601 Pages count : 5 DOI: 10.1007/BF00958003

Authors

Reznikov V.A. ¹ , Urzhuntseva I.A. ¹ , Volodarskii L.B. ¹

Affiliations

1	Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

It was shown that the recyclization of enamino ketones (hydrogenated derivatives of benzimidazole), which proceeds in an acid medium, leads to 6-azabicyclo[3.2.1]-oct-6-en-8-ones. The reactions of these with nucleophilic reagents proceed primarily at the carbonyl group, while reactions with an excess of organometallic reagents with subsequent oxidation lead to stable nitroxide radicals (derivatives of 6-azabicyclo[3.2.l]octane).

Reznikov V.A. , Urzhuntseva I.A. , Volodarskii L.B.
SYNTHESIS OF BICYCLIC BETA-OXO NITRONES - DERIVATIVES OF 6-AZABICYCLO[3.2.1]OCTANE AND THEIR REACTIONS WITH NUCLEOPHILIC-REAGENTS
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1991. V.40. N3. P.597-601. DOI: 10.1007/BF00958003 WOS Scopus РИНЦ OpenAlex

Published print:

Mar 1, 1991

≡ Web of science:	WOS:A1991GM58500009
≡ Scopus:	2-s2.0-4544238536
≡ Elibrary:	30942089
≡ OpenAlex:	W1967789347