Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystals

Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystals Full article

Journal

Journal of Materials Chemistry C
ISSN: 2050-7534

Output data

Year: 2019, Volume: 7, Number: 1, Pages: 60-68 Pages count : 9 DOI: 10.1039/c8tc04151b

Authors

Mannanov Artur A. ^1,2,3 , Kazantsev Maxim S. ^4,5 , Kuimov Anatoly D. ^4,5 , Konstantinov Vladislav G. ^2,3,6 , Dominskiy Dmitry I. ^2,3,6 , Trukhanov Vasiliy A. ^2,3,6 , Anisimov Daniil S. ^2,3,6 , Gultikov Nikita V. ^2,3 , Bruevich Vladimir V. ^2,3,6 , Koskin Igor P. ^4,5 , Sonina Alina A. ^4,5 , Rybalova Tatyana V. ^4,5 , Shundrina Inna K. ^4,5 , Mostovich Evgeny A. ^4,5 , Paraschuk Dmitry Yu. ^2,3,6 , Pshenichnikov Maxim S. ¹

Affiliations

1	(Данные Web of science) Univ Groningen, Zernike Inst Adv Mat, Opt Condensed Matter Phys Grp, Nijenborgh 4, NL-9747 AG Groningen, Netherlands
2	(Данные Web of science) Lomonosov Moscow State Univ, Fac Phys, Leninskie Gory 1-62, Moscow 119991, Russia
3	(Данные Web of science) Lomonosov Moscow State Univ, Ctr Int Laser, Leninskie Gory 1-62, Moscow 119991, Russia
4	(Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem, Lavrentieva 9, Novosibirsk 630090, Russia
5	(Данные Web of science) Novosibirsk State Univ, Pirogova 2, Novosibirsk 630090, Russia
6	(Данные Web of science) Russian Acad Sci, Enikolopov Inst Synthet Polymer Mat, Profsoyuznaya 70, Moscow 117393, Russia

The design of light-emitting crystalline organic semiconductors for optoelectronic applications requires a thorough understanding of the singlet exciton transport process. In this study, we show that the singlet exciton diffusion length in a promising semiconductor crystal based on furan/phenylene co-oligomers is 24 nm. To achieve this, we employed the photoluminescence quenching technique using a specially synthesized quencher, which is a long furan/phenylene co-oligomer that was facilely implanted into the host crystal lattice. Extensive Monte-Carlo simulations, exciton-exciton annihilation experiments and numerical modelling fully supported our findings. We further demonstrated the high potential of the furan/phenylene co-oligomer crystals for light-emitting applications by fabricating solution-processed organic light emitting transistors.

Mannanov A.A. , Kazantsev M.S. , Kuimov A.D. , Konstantinov V.G. , Dominskiy D.I. , Trukhanov V.A. , Anisimov D.S. , Gultikov N.V. , Bruevich V.V. , Koskin I.P. , Sonina A.A. , Rybalova T.V. , Shundrina I.K. , Mostovich E.A. , Paraschuk D.Y. , Pshenichnikov M.S.
Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystals
Journal of Materials Chemistry C. 2019. V.7. N1. P.60-68. DOI: 10.1039/c8tc04151b WOS Scopus РИНЦ OpenAlex

Web of science:	WOS:000454087900019
Scopus:	2-s2.0-85059086775
Elibrary:	38628793
OpenAlex:	W2895959381

DB	Citing
Web of science	21
Scopus	21
Elibrary	22
OpenAlex	23