The effect of the oxophilic Tb(III) cation on C-ON bond homolysis in alkoxyamines Научная публикация
| Журнал |
Inorganic Chemistry Communications
ISSN: 1387-7003 |
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| Вых. Данные | Год: 2018, Том: 91, Страницы: 5-7 Страниц : 3 DOI: 10.1016/j.inoche.2018.02.019 | ||||||
| Ключевые слова | Homolysis of alkoxyamines; Alkoxyamine-Tb(III) complex; Dlethylphosphoryl group-Tb coordination; Safe radical polymerization initiator | ||||||
| Авторы |
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Реферат:
Recently, we reported on the activation of the C-ON bond homolysis in alkoxyamines R1R2NOR3 using the coordination of the alkyl fragment R-3 with metal cations Cu(II) and Zn(II). Here, we report the selective coordination of the diethylphosphoryl group carried by the nitroxyl fragment by the oxophilic metal cation Tb(III). Coordination on the nitroxyl fragment afford a slight 2-fold decrease in the C-ON bond homolysis rate constant kd. (C) 2018 Elsevier B.V. All rights reserved.
Библиографическая ссылка:
Audran G.
, Bagryanskaya E.G.
, Bagryanskaya I.Y.
, Edeleva M.
, Kaletina P.
, Marque S.R.A.
, Parkhomenko D.
, Tretyakov E.V.
, Zhivetyeva S.I.
The effect of the oxophilic Tb(III) cation on C-ON bond homolysis in alkoxyamines
Inorganic Chemistry Communications. 2018. V.91. P.5-7. DOI: 10.1016/j.inoche.2018.02.019 WOS Scopus РИНЦ OpenAlex
The effect of the oxophilic Tb(III) cation on C-ON bond homolysis in alkoxyamines
Inorganic Chemistry Communications. 2018. V.91. P.5-7. DOI: 10.1016/j.inoche.2018.02.019 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 мая 2018 г. |
Идентификаторы БД:
| Web of science: | WOS:000430904400002 |
| Scopus: | 2-s2.0-85042850285 |
| РИНЦ: | 35509237 |
| OpenAlex: | W2793368379 |