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Reaction of Perfluorobenzocyclobutene with Excess Pentafluorobenzene in SbF5 Full article

Journal Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393
Output data Year: 2018, Volume: 54, Number: 4, Pages: 545-553 Pages count : 9 DOI: 10.1134/S107042801804005X
Authors Mezhenkova T.V. 1 , Sinyakov V.R. 1 , Karpov V.M. 1 , Zonov Ya.V. 1,2 , Gatilov Yu.V. 1,2 , Platonov V.E. 1
Affiliations
1 (Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, Ul Pirogova 1, Novosibirsk 630090, Russia

Abstract: The reaction of perfluorobenzocyclobutene with excess pentafluorobenzene in SbF5, followed by hydrolysis, gave a mixture of perfluoro-1,3,3-triphenyl-1,3-dihydro-2-benzofuran-1-ol, perfluoro-1,1,2-triphenylbenzocyclobuten- 5-one, and perfluoro-4-(2,2-diphenylbenzocyclobuten-1-ylidene)cyclohexa-2,5-dien-1- one. When the reaction mixture was treated for a long time with Olah's reagent (HF-pyridine), isomeric perfluoro-9,10-diphenyl-1,4-, -1,10-, -2,9-, and -9,10-dihydroanthracenes were formed and were converted to perfluoro-9,10-diphenylanthracene by the action of SbF5.
Cite: Mezhenkova T.V. , Sinyakov V.R. , Karpov V.M. , Zonov Y.V. , Gatilov Y.V. , Platonov V.E.
Reaction of Perfluorobenzocyclobutene with Excess Pentafluorobenzene in SbF5
Russian Journal of Organic Chemistry. 2018. V.54. N4. P.545-553. DOI: 10.1134/S107042801804005X WOS Scopus РИНЦ OpenAlex
Original: Меженкова Т.В. , Синяков В.Р. , Карпов В.М. , Зонов Я.В. , Гатилов Ю.В. , Платонов В.Е.
Взаимодействие перфторбензоциклобутена с избытком пентафторбензола в sbf5
Журнал органической химии (RUSS J ORG CHEM+). 2018. Т.54. №4. С.546-553. РИНЦ
Dates:
Published print: Apr 1, 2018
Published online: Jun 6, 2018
Identifiers:
Web of science: WOS:000434488900005
Scopus: 2-s2.0-85048107989
Elibrary: 35734610
OpenAlex: W2806184829
Citing:
DB Citing
Web of science 3
Scopus 2
Elibrary 5
OpenAlex 3
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