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Synthesis and Optical Properties of Alkaloid Quindoline, Its Structural Analogues and Substituted delta-Carbolines Full article

Journal ChemistrySelect
ISSN: 2365-6549
Output data Year: 2019, Volume: 4, Number: 5, Pages: 1696-1699 Pages count : 4 DOI: 10.1002/slct.201803515
Tags Cadogan cyclization; delta-carboline; fluorescence; nitropyridine; quindoline
Authors Shuvalov Vladislav Yu 1,2 , Rupp Anna S. 1 , Fisyuk Alexander S. 1,2 , Kuratova Anna K. 1 , Nefedov Andrey A. 3 , Sagitullina Galina P. 1
Affiliations
1 (Данные Web of science) FM Dostoevsky Omsk State Univ, Dept Organ Chem, 55a Mira Ave, Omsk 644077, Russia
2 (Данные Web of science) Omsk State Tech Univ, Lab New Organ Mat, 11 Mira Ave, Omsk 644050, Russia
3 (Данные Web of science) Russian Acad Sci, NN Vorozhtsov Inst Organ Chem, Siberian Branch, 9 Lavrentiev Ave, Novosibirsk 630090, Russia

Abstract: Alkaloid quindoline, its structural analogues and delta-carbolines were obtained through the Cadogan reaction using DPPE under solvent-free conditions as a key stage of the synthesis. Various o-nitroarylpyridines prepared by one-pot synthesis from nitroacetophenones, methyl orthoformate and acetoacetic ester enamine were used as starting materials for the preparation of delta-carbolines. 2-Aryl-3-nitro-5,6,7,8-tetrahydroquinolines obtained by reacting 2-hydroxymethylenecyclohexanone with nitroacetophenones enamines were used for the synthesis of quindoline and its structural analogs. A relationship between the structure and optical properties of the synthesized compounds was found.
Cite: Shuvalov V.Y. , Rupp A.S. , Fisyuk A.S. , Kuratova A.K. , Nefedov A.A. , Sagitullina G.P.
Synthesis and Optical Properties of Alkaloid Quindoline, Its Structural Analogues and Substituted delta-Carbolines
ChemistrySelect. 2019. V.4. N5. P.1696-1699. DOI: 10.1002/slct.201803515 WOS Scopus РИНЦ OpenAlex
Dates:
Published online: Feb 4, 2019
Published print: Feb 7, 2019
Identifiers:
Web of science: WOS:000458164500018
Scopus: 2-s2.0-85061188531
Elibrary: 38680910
OpenAlex: W2912886200
Citing:
DB Citing
Web of science 15
Scopus 17
Elibrary 15
OpenAlex 17
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